Effects of Catalyst Pore Structure and Acid Properties on the Dehydration of Glycerol

被引：40

作者：

Choi, Youngbo ^{[1
]}

Park, Hongseok ^{[1
]}

Yun, Yang Sik ^{[1
]}

Yi, Jongheop ^{[1
]}

机构：

[1] Seoul Natl Univ, World Class Univ Program Chem Convergence Energy, Inst Chem Proc, Sch Chem & Biol Engn, Seoul 151742, South Korea

来源：

CHEMSUSCHEM | 2015年 / 8卷 / 06期

基金：

新加坡国家研究基金会;

关键词：

biomass; dehydration; heterogeneous catalysis; mesoporous materials; nanoparticles; GAS-PHASE DEHYDRATION; SUSTAINABLE PRODUCTION; ACROLEIN; SILICA;

D O I：

10.1002/cssc.201402925

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hierarchical porous catalysts have recently attracted increasing interest because of the enhanced accessibility to active sites on such materials. In this context, previously reported hierarchically mesoporous ASN and ASPN materials are evaluated by applying them to the dehydration of glycerol, and demonstrate excellent catalytic performance. In addition, a comprehensive understanding of the effects of pore structures and the acid properties on the reaction through comparative studies with microporous HZSM-5 and mesoporous AlMCM-41 is provided.

引用

页码：974 / 979

页数：6

共 36 条

[1] Gas-phase dehydration of glycerol to acrolein catalysed by caesium heteropoly salt [J].

Alhanash, Abdullah ;

Kozhevnikova, Elena F. ;

Kozhevnikov, Ivan V. .

APPLIED CATALYSIS A-GENERAL, 2010, 378 (01) :11-18

[2] Dehydration of glycerol in gas phase using heteropolyacid catalysts as active compounds [J].

Atia, Hanan ;

Armbruster, Udo ;

Martin, Andreas .

JOURNAL OF CATALYSIS, 2008, 258 (01) :71-82

[3] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].

BECK, JS ;

VARTULI, JC ;

ROTH, WJ ;

LEONOWICZ, ME ;

KRESGE, CT ;

SCHMITT, KD ;

CHU, CTW ;

OLSON, DH ;

SHEPPARD, EW ;

MCCULLEN, SB ;

HIGGINS, JB ;

SCHLENKER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843

[4] Improved utilisation of renewable resources: New important derivatives of glycerol [J].

Behr, Arno ;

Eilting, Jens ;

Irawadi, Ken ;

Leschinski, Julia ;

Lindner, Falk .

GREEN CHEMISTRY, 2008, 10 (01) :13-30

[5]

Blauwhoff P.M.M., 1999, Catalysis and Zeolites: Fundamentals and Applications, P437

[6] Sustainable production of acrolein: investigation of solid acid-base catalysts for gas-phase dehydration of glycerol [J].

Chai, Song-Hai ;

Wang, Hao-Peng ;

Liang, Yu ;

Xu, Bo-Qing .

GREEN CHEMISTRY, 2007, 9 (10) :1130-1136

[7] A facile approach for the preparation of tunable acid nano-catalysts with a hierarchically mesoporous structure [J].

Choi, Youngbo ;

Yun, Yang Sik ;

Park, Hongseok ;

Park, Dae Sung ;

Yun, Danim ;

Yi, Jongheop .

CHEMICAL COMMUNICATIONS, 2014, 50 (57) :7652-7655

[8] Mesoporous Siliconiobium Phosphate as a Pure Bronsted Acid Catalyst with Excellent Performance for the Dehydration of Glycerol to Acrolein [J].

Choi, Youngbo ;

Park, Dae Sung ;

Yun, Hyeong Jin ;

Baek, Jayeon ;

Yun, Danim ;

Yi, Jongheop .

CHEMSUSCHEM, 2012, 5 (12) :2460-2468

[9] INORGANIC SOLID ACIDS AND THEIR USE IN ACID-CATALYZED HYDROCARBON REACTIONS [J].

CORMA, A .

CHEMICAL REVIEWS, 1995, 95 (03) :559-614

[10] Chemical routes for the transformation of biomass into chemicals [J].

Corma, Avelino ;

Iborra, Sara ;

Velty, Alexandra .

CHEMICAL REVIEWS, 2007, 107 (06) :2411-2502

← 1 2 3 4 →