Diaqua(2,2′-bipyridine-κ2N,N′)bis(perchlorato-κO)copper(II)

被引：2

作者：

Damous, Maamar ^{[1
]}

Hamlaoui, Meriem ^{[1
]}

Bouacida, Sofiane ^{[1
]}

Merazig, Hocine ^{[1
]}

Daran, Jean-Claude ^{[2
]}

机构：

[1] Univ Mentouri Constantine, Unite Rech Chim Environm & Mol Struct, CHEMS, Constantine 25000, Algeria

[2] CNRS, Chim Coordinat Lab, UPR 8241, F-31077 Toulouse, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

GRAPH-SET ANALYSIS; CRYSTALS; PATTERNS;

D O I：

10.1107/S1600536811013808

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The central CuN2O4 motif of the title compound, [Cu(ClO4)(2)(C10H8N2)(H2O)(2)], exhibits a Jahn-Teller-distorted octahedral geometry around the metal atom, showing a considerably long Cu-O bond distance of 2.5058 (12) angstrom towards the second perchlorate group, giving a (4 + 1+1)-type coordination mode. In the crystal, the components are linked via intermolecular O-H center dot center dot center dot O hydrogen bonds, forming layers parallel to (001). Additional stabilization within these layers is provided by pi-pi [centroid-centroid distances of 3.7848 (9)-4.4231 (9) angstrom] stacking interactions.

引用

页码：M611 / U991

页数：13

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