Recent Advances in the Transition Metal-Catalyzed Addition of Carboxylic Acids to Alkynes

被引：7

作者：

Cadierno, Vittorio ^{[1
]}

机构：

[1] Univ Oviedo, Fac Quim, Dept Quim Organ & Inorgan, E-33006 Oviedo, Spain

来源：

CURRENT ORGANIC CHEMISTRY | 2021年 / 25卷 / 20期

关键词：

Enol esters; lactones; alkynes; hydro-oxycarbonylation reactions; cycloisomerization reactions; metal-catalyzed transformations; ONE-POT SYNTHESIS; ANTI-MARKOVNIKOV ADDITION; CARBON-DIOXIDE INCORPORATION; O-DIENYL ESTERS; TERMINAL ALKYNES; ENOL ESTERS; ASYMMETRIC HYDROFORMYLATION; STEREOSELECTIVE ADDITION; EFFICIENT SYNTHESIS; SELECTIVE ADDITION;

D O I：

10.2174/1385272825666210308113837

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recent advances in the metal-catalyzed hydrofunctionalization of alkynes with carboxylic acids are comprehensively reviewed. Both inter- and intramolecular processes, leading respectively to enol esters and lactones, are discussed, as well as the involvement of these transformations in the synthesis of natural products and biologically active molecules, and the assembly of elaborated heterocyclic compounds through cascade processes. Literature published since 2011 is covered.

引用

页码：2260 / 2303

页数：44

共 205 条

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