Anion-π interactions in five-membered rings:: a combined crystallographic and ab initio study

被引：0

作者：

Garau, C ^{[1
]}

Frontera, A ^{[1
]}

Quiñonero, D ^{[1
]}

Ballester, P ^{[1
]}

Costa, A ^{[1
]}

Deyà, PM ^{[1
]}

机构：

[1] Univ Illes Balears, Dept Quim, Palma de Mallorca 07122, Spain

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 382卷 / 5-6期

关键词：

D O I：

10.1016/j.cplett.2003.10.056

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have carried out searches on the Cambridge Structural Database in order to find anion-pi contacts in five-membered aromatic rings. The results indicate that anion-pi interactions are possible between anions and the cyclopentadienyl ligand in eta(5)-transition metal complexes. Ab initio calculations confirm the suitability of the interaction. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：534 / 540

页数：7

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