Benzene-1,3,5-triyl triformate (TFBen): a convenient, efficient, and non-reacting CO source in carbonylation reactions

被引：83

作者：

Jiang, Li-Bing ^{[1
]}

Qi, Xinxin ^{[1
]}

Wu, Xiao-Feng ^{[1
,2
]}

机构：

[1] Zhejiang Sci Tech Univ, Dept Chem, Xiasha Campus, Hangzhou 310018, Zhejiang, Peoples R China

[2] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

TETRAHEDRON LETTERS | 2016年 / 57卷 / 30期

关键词：

Palladium catalyst; Carbonylation; Aryl formates; Benzene-1,3,5-triol; CO surrogate; PALLADIUM-CATALYZED CARBONYLATION; CARBON-MONOXIDE SOURCE; KHAND-TYPE REACTION; ARYL HALIDES; FORMIC-ACID; REDUCTIVE CARBONYLATION; FORMATE; ALDEHYDES; IODIDES; ALKENES;

D O I：

10.1016/j.tetlet.2016.06.071

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzene-1,3,5-triyl triformate (TFBen) as a kind of convenient and efficient CO source has been prepared for the first time. The character of TFBen as potent and non-reacting CO source has been proven by the successful synthetic applications in carbonylation reactions. Phloroglucinol (1,3,5-trihydroxybenzene) is abundant and naturally occurring has been applied as the reusable material for TFBen synthesis. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：3368 / 3370

页数：3

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