Photocatalytic CO2 reduction in metal-organic frameworks: A mini review

被引:141
作者
Wang, Chong-Chen [1 ,2 ]
Zhang, Yan-Qiu [1 ]
Li, Jin [1 ]
Wang, Peng [1 ]
机构
[1] Beijing Univ Civil Engn & Arch, Key Lab Urban Stormwater Syst & Water Environm, Minist Educ, Beijing 100044, Peoples R China
[2] Beijing Univ Civil Engn & Arch, Beijing Climate Change Response Res & Educ Ctr, Beijing 100044, Peoples R China
基金
北京市自然科学基金;
关键词
Metal-organic frameworks; Carbon dioxide; Photocatalytic; Reduction; CARBON-DIOXIDE; SILVER(I) COMPLEXES; HYDROGEN STORAGE; HYDROTHERMAL SYNTHESIS; CARBOXYLIC-ACID; WATER; SEMICONDUCTOR; MOFS; CATALYSIS; ADSORPTION;
D O I
10.1016/j.molstruc.2014.11.036
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Photocatalytic reduction of CO2 for value-added chemicals is an attractive process to address both energy and environmental issues. This mini review paper presents two different conversion processes, namely conversion to organic chemicals (like CH4, CH3OH, HCOOH and so on) and being split into CO, in metal-organic frameworks (MOFs). The reported examples are collected and analyzed; and the reaction mechanism, the influence of various factors on the photocatalytic performance, the involved challenges, and the prospects are discussed and estimated. It is clear that MOFs have a bright prospect in the field of photocatalytic reduction of CO2. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:127 / 136
页数:10
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