Evidence for radical fragmentations from persistent singlet carbenes

被引：19
作者：
Cattoën, X
Miqueu, K
Gornitzka, H
Bourissou, D
Bertrand, G
机构：
[1] Univ Toulouse 3, Lab Heterochim Fondamentale & Appl, UMR 5069, F-31062 Toulouse, France
[2] Univ Calif Riverside, Dept Chem, UCR CNRS Joint Res Chem Lab, UMR 2282, Riverside, CA 92521 USA
[3] Univ Pau & Pays Adour, UMR 5624, Lab Chim Theor & Physicochim Mol, F-64013 Pau, France
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 10期
关键词：
D O I：
10.1021/ja050028g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Upon warm up, persistent aminohydrazinocarbenes undergo β-fragmentation reactions. Experimental as well as computational evidences are reported for the involvement of radical processes. This is the first example of a homolytic fragmentation for a persistent singlet carbene. Copyright © 2005 American Chemical Society.
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收藏
页码：3292 / 3293
页数：2
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