Analysis of charcoal blast furnace slags by laser-induced breakdown spectroscopy

被引:7
作者
Bhatt, Chet R. [1 ,2 ]
Goueguel, Christian L. [1 ]
Jain, Jinesh C. [3 ]
Edenborn, Harry M. [1 ]
McIntyre, Dustin L. [1 ]
机构
[1] US DOE, Natl Energy Technol Lab, Pittsburgh, PA 15236 USA
[2] Mississippi State Univ, Dept Phys & Astron, Starkville, MS 39762 USA
[3] AECOM Technol Corp, Natl Energy Technol Lab, Pittsburgh, PA 15236 USA
关键词
RARE-EARTH-ELEMENTS; SPACE EXPLORATION; IRON OBJECTS; STEEL WORKS; ICP-MS; LIBS; SPECTROMETRY; UNIVARIATE; SPECTRA; SAMPLES;
D O I
10.1364/AO.56.007789
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Laser-induced breakdown spectroscopy (LIBS) was used for the analysis of charcoal blast furnace slags. Plasma was generated by an application of a 1064 nm wavelength Nd:YAG laser beam to the surface of pellets created from the slags. The presence of Al, Ca, Fe, K, Mg, Mn, and Si was determined by identifying their characteristic spectral signatures. Multivariate analysis was performed for the quantification of these elements. The predicted LIBS results were found in agreement with the inductively coupled plasma optical emission spectrometry analysis. The limit of detection for Al, Ca, Fe, K, Mg, Mn, and Si was calculated to be 0.10%, 0.22%, 0.02%, 0.01%, 0.01%, 0.005%, and 0.18%, respectively. (C) 2017 Optical Society of America
引用
收藏
页码:7789 / 7795
页数:7
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