Icosahedral clusters, icosaheral order and stability of quasicrystals - a view of metallurgy

被引:115
作者
Tsai, An Pang [1 ,2 ]
机构
[1] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan
[2] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan
关键词
stable quasicrystal; isodahedral cluster; valence concentration; phason disorder; icosahedral order;
D O I
10.1088/1468-6996/9/1/013008
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We review the stability of various icosahedral quasicrystals ( iQc) from a metallurgical viewpoint. The stability of stable iQcs is well interpreted in terms of Hume-Rothery rules, i.e. atomic size factor and valence electron concentration, e/a. For metastable iQcs, we discuss the role of phason disorder introduced by rapid solidification, in structural stability and its interplay with chemical order and composition.
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页数:20
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