Mixture of HIBA and glycolic acid as eluent for effective separation of yttrium and dysprosium by HPLC

被引:12
|
作者
Wu, HZ
Watanabe, N
Gohshi, Y
Kotama, R
机构
[1] Univ Tokyo, Grad Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 113, Japan
[2] Sumitomo Met Min Co Ltd, Cent Res Lab, Chiba 272, Japan
来源
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1999年 / 363卷 / 04期
关键词
D O I
10.1007/s002160051214
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A mixture of 2-hydroxy-2-methylpropanoic acid (HIBA) and glycolic acid, with 1-octanesulfonate (OS) as hydrophobic ion proved to be successful for the separation of rare-earth elements (REE), UI the ratio of HIBA and glycolic acid is suitably adjusted, it is possible to separate Y from Dy. The resolution of Y and Dy was further improved by controlling the concentration of HIBA and glycolic acid. The technique was applied successfully to the separation and analysis of highly pure Y2O3 and DY2O3.
引用
收藏
页码:424 / 426
页数:3
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