Conversion of glucose into 5-hydroxymethylfurfural with boric acid in molten mixtures of choline salts and carboxylic acids

被引：47

作者：

Matsumiya, Hiroaki ^{[1
]}

Hara, Takeyoshi ^{[2
]}

机构：

[1] Nagoya Univ, EcoTopia Sci Inst, Div Green Convers, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[2] Nagoya Univ, Grad Sch Engn, Dept Mat Sci & Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

BIOMASS & BIOENERGY | 2015年 / 72卷

关键词：

5-Hydroxymethylfurfural; Glucose; Boric acid; Choline dihydrogen citrate; Glycolic acid; Ionic liquid; CATALYSTS; BIOMASS; CELLULOSE; CHLORIDE; SUGARS;

D O I：

10.1016/j.biombioe.2014.11.001

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

The conversion of glucose into a potential platform chemical for fuels and plastics, 5-hydroxymethylfurfural (HMF), has been studied using B(OH)(3) as a promoter in different solvents, namely molten mixtures made of choline salts and carboxylic acids, with the aim of developing an inexpensive and less harmful alternative to Cr/ionic liquid systems. Choline chloride-based molten mixtures afforded poor yields of HMF, whereas the yields were improved by replacing choline chloride with choline dihydrogen citrate. The combination of choline dihydrogen citrate and glycolic acid was the best choice, providing an HMF yield of similar to 60% at 140 degrees C within 4 h by adding a small volume of water as a co-solvent. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：227 / 232

页数：6

共 25 条

[1] Electrodeposition of zinc-tin alloys from deep eutectic solvents based on choline chloride [J].

Abbott, Andrew P. ;

Capper, Glen ;

McKenzie, Katy J. ;

Ryder, Karl S. .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2007, 599 (02) :288-294

[2] Cationic functionalisation of cellulose using a choline based ionic liquid analogue [J].

Abbott, Andrew P. ;

Bell, Thomas J. ;

Handa, Sandeep ;

Stoddart, Barry .

GREEN CHEMISTRY, 2006, 8 (09) :784-786

[3] O-acetylation of cellulose and monosaccharides using a zinc based ionic liquid [J].

Abbott, AP ;

Bell, TJ ;

Handa, S ;

Stoddart, B .

GREEN CHEMISTRY, 2005, 7 (10) :705-707

[4] Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].

Abbott, AP ;

Boothby, D ;

Capper, G ;

Davies, DL ;

Rasheed, RK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147

[5] Chromium(III) catalysts in ionic liquids for the conversion of glucose to 5-(hydroxymethyl)furfural (HMF): Insight into metal catalyst:ionic liquid mediated conversion of cellulosic biomass to biofuels and chemicals [J].

Bali, Sumit ;

Tofanelli, Marcus A. ;

Ernst, Richard D. ;

Eyring, Edward M. .

BIOMASS & BIOENERGY, 2012, 42 :224-227

[6] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].

Bozell, Joseph J. ;

Petersen, Gene R. .

GREEN CHEMISTRY, 2010, 12 (04) :539-554

[7] The CO2-assisted autohydrolysis of wheat straw [J].

da Silva, Sara P. Magalhaes ;

Morais, Ana Rita C. ;

Bogel-Lukasik, Rafal .

GREEN CHEMISTRY, 2014, 16 (01) :238-246

[8] 12-Tungstophosphoric acid/boric acid as synergetic catalysts for the conversion of glucose into 5-hydroxymethylfurfural in ionic liquid [J].

Hu, Lei ;

Sun, Yong ;

Lin, Lu ;

Liu, Shijie .

BIOMASS & BIOENERGY, 2012, 47 :289-294

[9] Efficient conversion of glucose into 5-hydroxymethylfurfural catalyzed by a common Lewis acid SnCl4 in an ionic liquid [J].

Hu, Suqin ;

Zhang, Zhaofu ;

Song, Jinliang ;

Zhou, Yinxi ;

Han, Buxing .

GREEN CHEMISTRY, 2009, 11 (11) :1746-1749

[10] Direct conversion of glucose and cellulose to 5-hydroxymethylfurfural in ionic liquid under microwave irradiation [J].

Li, Changzhi ;

Zhang, Zehui ;

Zhao, Zongbao K. .

TETRAHEDRON LETTERS, 2009, 50 (38) :5403-5405

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