A mild aldol reaction of aryl aldehydes through palladium-catalyzed hydrosilation of α,β-unsaturated carbonyl compounds with trichlorosilane

被引：59

作者：

Kiyooka, S ^{[1
]}

Shimizu, A ^{[1
]}

Torii, S ^{[1
]}

机构：

[1] Kochi Univ, Fac Sci, Dept Chem, Akebono, Kochi 7808520, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 29期

关键词：

D O I：

10.1016/S0040-4039(98)01030-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mild aldol reaction of aryl aldehydes took place by using N,N-dimethylacrylamide and trichlorosilane with a catalytic amount of tetrakis(triphenylphosphine)palladium. A unique anti selectivity was observed in the reaction. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：5237 / 5238

页数：2

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