Outstanding vapochromism and pH-dependent coloration of dicyano(4,4′-dicarboxy-2,2′-bipyridine)platinum(II) with a three-dimensional network structure

被引：56

作者：

Kato, M ^{[1
]}

Kishi, S

Wakamatsu, Y

Sugi, Y

Osamura, Y

Koshiyama, T

Hasegawa, M

机构：

[1] Nara Womens Univ, Grad Sch Humanities & Sci, Div Mat Sci, Nara 6308506, Japan

[2] Aoyama Gakuin Univ, Coll Sci & Engn, Dept Chem & Biol Sci, Sagamihara, Kanagawa 2298558, Japan

来源：

CHEMISTRY LETTERS | 2005年 / 34卷 / 10期

关键词：

D O I：

10.1246/cl.2005.1368

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dicyano(4,4'-dicarboxy-2,2'-bipyridine)platinum(II) forms pH-dependent polymorphs of various colors and displays outstanding vapochromism followed by luminescence changes upon exposure to certain organic vapors. The high sensitivity of the complex to vapor and pH is related to its three-dimensional network structure, which includes large cavities formed by hydrogen bonds and Pt center dot center dot center dot Pt interactions.

引用

页码：1368 / 1369

页数：2

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