(Acetonitrile-κN)[2-(diphenylphosphanyl)ethanamine-κ2N,P][(1,2,3,4,5-η)1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate

被引：0

作者：

Lee, Kajin ^{[1
]}

Rominger, Frank ^{[2
]}

Limbach, Michael ^{[1
]}

机构：

[1] CaRLa Catalysis Res Lab, D-69120 Heidelberg, Germany

[2] Univ Heidelberg, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

CP-ASTERISK-RU(PN) COMPLEX; ASYMMETRIC-SYNTHESIS; HYDROGENATION; PHOSPHINES; LIGANDS;

D O I：

10.1107/S1600536811028832

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title cationic Cp*Fe(II) complex, [Fe(C10H15)(CH13CN)-( C14H16NP)] PF6 center dot C4H8O, the metal ion is coordinated by the eta(5)-Cp* ring as well as the P and N atoms of the chelating 2-(diphenylphosphino) ethylamine ligand and an additional acetonitrile molecule in a piano- chair conformation. The PF6- anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.221 (7).

引用

页码：M1135 / U1176

页数：14

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