Liquid-liquid equilibrium for ternary systems of propyl vinyl ether plus C3 or C4 alcohols plus water at 298.15 K and excess molar enthalpies for ternary and constituent binary systems of propyl vinyl ether plus ethanol plus isooctane at 303.15 K

被引:6
作者
Hwang, In-Chan [1 ]
Kim, Jae-K [1 ]
Park, So-Jin [1 ]
In, Se-Jin [2 ]
机构
[1] Chungnam Natl Univ, Dept Chem Engn, Coll Engn, Taejon 305764, South Korea
[2] Woosong Univ, Dept Fire & Protect Engn, Taejon 300718, South Korea
关键词
D O I
10.1021/je7005743
中图分类号
O414.1 [热力学];
学科分类号
摘要
Liquid-liquid equilibrium (LLE) data for the ternary systems of propyl vinyl ether + C-3 or C-4 alcohols (1-propanol, 2-propanol, 1-butanol, and 2-butanol) + water at 298.15 K were analytically determined by using stirred and thermoregulated cells. Experimental LLE data were correlated with the NRTL and UNIQUAC equations. The distribution and selectivity Of C3 or C4 alcohols as a solvent were analyzed. Additionally, excess molar enthalpies at 303.15 K are reported for the binary systems of propyl vinyl ether + ethanol, ethanol + isooctane, and propyl vinyl ether + isooctane. These data were obtained by using an isothermal flow calorimeter. The isocline of excess molar enthalpies for the ternary system of propyl vinyl ether + ethanol + isooctane at 303.15 K was calculated using the Radojkovic equation.
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页码:475 / 480
页数:6
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