Copper-Porphyrin-Metal-Organic Frameworks as Oxidative Heterogeneous Catalysts

被引：29

作者：

Castro, Kelly A. D. F. ^{[1
,2
,3
]}

Figueira, Flavio ^{[2
,3
]}

Mendes, Ricardo F. ^{[3
,4
]}

Cavaleiro, Jose A. S. ^{[2
,3
]}

Neves, Maria da Graca P. M. S. ^{[2
,3
]}

Simoes, Mario M. Q. ^{[2
,3
]}

Almeida Paz, Filipe A. ^{[3
,4
]}

Tome, Joao P. C. ^{[2
,3
,5
]}

Nakagaki, Shirley ^{[1
]}

机构：

[1] Univ Fed Parana UFPR, Lab Quim Bioinorgan & Catalise, CP 19081, BR-81531990 Curitiba, Parana, Brazil

[2] Univ Aveiro, QOPNA, P-3810193 Aveiro, Portugal

[3] Univ Aveiro, Dept Quim, P-3810193 Aveiro, Portugal

[4] Univ Aveiro, CICECO, Inst Mat Aveiro, P-3810193 Aveiro, Portugal

[5] Univ Lisbon, Inst Super Tecn, Dept Engn Quim, Ctr Quim Estrut, P-1049001 Lisbon, Portugal

来源：

CHEMCATCHEM | 2017年 / 9卷 / 15期

关键词：

copper; heterogeneous catalysis; metal-organic frameworks; oxidation; porphyrins; METALLOPORPHYRIN DERIVATIVES; BIOMIMETIC CATALYSTS; HIGHLY EFFICIENT; FEATURES; PHTHALOCYANINES; RECOGNITION; COMPLEXES; MODELS;

D O I：

10.1002/cctc.201700484

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis and structural characterization of novel metal-organic-framework-type materials obtained from the reaction of 5,10,15,20-tetrakis[ 2,3,5,6-tetrafluoro-4-(4-pyridylsulfanyl) phenyl] porphyrin (H(2)P1) and 5,10,15,20-tetrakis(4-pyridyl) porphyrin (H(2)P2) with copper(II) acetate is reported. The new material, CuP1S, shows higher heterogeneous catalytic activity than the homogeneous porphyrin-copper(II) complex CuP1 in the oxidation of catechol into ortho-benzoquinone in the presence of air (O-2) or H2O2 (30 %).

引用

页码：2939 / 2945

页数：7

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