Structure and magnetic properties of a chiral two-dimensional ferrimagnet with Tc of 38 K

被引：201
作者：
Inoue, K [1 ]
Kikuchi, K
Ohba, M
Ökawa, H
机构：
[1] Okazaki Natl Res Inst, Inst Mol Sci, Dept Appl Mol Sci 1, Okazaki, Aichi 4448585, Japan
[2] Tokyo Metropolitan Univ, Dept Chem, Hachioji, Tokyo 1920367, Japan
[3] Kyushu Univ, Grad Sch Sci, Dept Chem, Fukuoka 8128581, Japan
[4] Kyushu Univ, Grad Sch Sci, Dept Chem, Fukuoka 8128581, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 39期
关键词：
chiral resolution; chromium; circular dichroism; magnetic properties; manganese;
D O I：
10.1002/anie.200351888
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Large single crystals of the chiral ferrimagnet [{Cr(CN) 6}{Mn(S)-pnH-(H2O)}](H2O) can be recovered from the reaction between K3[Cr(CN)6], Mn(ClO 4)2, and (S)-1,2-diaminopropane dihydrochloride (see picture). Magnetic measurements of the complex show that MnII and CrIII ions interact ferrimagnetically, with a magnetic transition occurring at 38 K.
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收藏
页码：4810 / 4813
页数：4
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