Highly efficient co-sensitization of nanocrystalline TiO2 electrodes with plural organic dyes

被引:192
作者
Chen, YS
Zeng, ZH
Li, C
Wang, WB
Wang, XS [1 ]
Zhang, BW
机构
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
关键词
D O I
10.1039/b502725j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Through cooperative interactions, each of the three organic dyes utilized achieved improved sensitizing abilities on nanocrystalline TiO2 electrodes in co-sensitization over single-dye-sensitization, which led to a wide ( 400 - 700 nm) and highly efficient ( exceeding 70%) photocurrent action spectrum in triple-dye-sensitization and an overall power conversion efficiency (eta) of 6.5% (AM1.5, 80 mW cm(-2)), the highest eta to date for dye-sensitized solar cells (DSSCs) based on the co-sensitization of plural organic dyes, fully demonstrating the potential of co-sensitization in DSSC applications.
引用
收藏
页码:773 / 776
页数:4
相关论文
共 20 条
  • [1] Improvement in photoelectric conversion of a phthalocyanine-sensitized TiO2 electrode by doping with porphyrin
    Deng, HH
    Lu, ZH
    Shen, YC
    Mao, HF
    Xu, HJ
    [J]. CHEMICAL PHYSICS, 1998, 231 (01) : 95 - 103
  • [2] Spectral sensitization of TiO2 nanocrystalline electrodes with aggregated cyanine dyes
    Ehret, A
    Stuhl, L
    Spitler, MT
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (41) : 9960 - 9965
  • [3] New perylenes for dye sensitization of TiO2
    Ferrere, S
    Gregg, BA
    [J]. NEW JOURNAL OF CHEMISTRY, 2002, 26 (09) : 1155 - 1160
  • [4] Gratzel M, 1991, NATURE, V353, P737, DOI DOI 10.1038/53737A0
  • [5] Dye-sensitized nanocrystalline TiO2 solar cells based on novel coumarin dyes
    Hara, K
    Tachibana, Y
    Ohga, Y
    Shinpo, A
    Suga, S
    Sayama, K
    Sugihara, H
    Arakawa, H
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2003, 77 (01) : 89 - 103
  • [6] CHARGE-SHIFT PROBES OF MEMBRANE-POTENTIAL - SYNTHESIS
    HASSNER, A
    BIRNBAUM, D
    LOEW, LM
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (14) : 2546 - 2551
  • [7] High efficiency of dye-sensitized solar cells based on metal-free indoline dyes
    Horiuchi, T
    Miura, H
    Sumioka, K
    Uchida, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (39) : 12218 - 12219
  • [8] ARTIFICIAL PHOTOSYNTHESIS .1. PHOTOSENSITIZATION OF TIO2 SOLAR-CELLS WITH CHLOROPHYLL DERIVATIVES AND RELATED NATURAL PORPHYRINS
    KAY, A
    GRATZEL, M
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (23) : 6272 - 6277
  • [9] Controlling dye (Merocyanine-540) aggregation on nanostructured TiO2 films.: An organized assembly approach for enhancing the efficiency of photosensitization
    Khazraji, AC
    Hotchandani, S
    Das, S
    Kamat, PV
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (22): : 4693 - 4700
  • [10] Phenyl-conjugated oligoene sensitizers for TiO2 solar cells
    Kitamura, T
    Ikeda, M
    Shigaki, K
    Inoue, T
    Anderson, NA
    Ai, X
    Lian, TQ
    Yanagida, S
    [J]. CHEMISTRY OF MATERIALS, 2004, 16 (09) : 1806 - 1812