New cardanol/sucrose epoxy blends for biobased coatings

被引：57
作者：
Darroman, Emilie [1 ]
Durand, Nelly [2 ]
Boutevin, Bernard [1 ]
Caillol, Sylvain [1 ]
机构：
[1] ENSCM, Inst Charles Gerhardt Montpellier, CNRS, Equipe IAM,UMR 5253,UM2,UM1, F-34296 Montpellier 5, France
[2] Sogatra Nouvelle, F-30350 Lezan, France
来源：
PROGRESS IN ORGANIC COATINGS | 2015年 / 83卷
关键词：
Epoxy resins; Cardanol; Sorbitol; Isosorbide; Biobased polymers; NUT-SHELL LIQUID; BISPHENOL-A; NOVOLAC RESINS; POLYMERS; VANILLIN; RISK;
D O I：
10.1016/j.porgcoat.2015.02.002
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Commercial epoxidized cardanol, from cashew nutshell liquid (CNSL) is a biobased reactant with interesting aromatic structure. Cured with two different amines, isophorone diamine and Jeffamine T403, the materials exhibit good properties but not enough to replace the bisphenol A diglycidyl ether (BADGE) in epoxy networks. Two kind of sucrose epoxy derivatives, sorbitol and isosorbide, were used as blends to enhance the properties of the epoxy cardanol-derived materials. These epoxy networks with different ratios were characterized by thermogravimetric analysis and differential scanning calorimetry; their hardness and brightness were measured as well as their resistance to chemical solvents. Biobased epoxy blends exhibit interesting properties for coating applications. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：47 / 54
页数：8
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