Recent advances in the synthesis of zirconium complexes and their catalytic applications

被引：7

作者：

Asim, Wasifa ^{[1
]}

Waheeb, Azal Shakir ^{[2
]}

Awad, Masar Ali ^{[2
]}

Kadhum, Afaf Murtada ^{[2
]}

Ali, Asjad ^{[1
]}

Mallah, Shaimaa Hassan ^{[2
]}

Iqbal, Muhammad Adnan ^{[1
,3
]}

Kadhim, Mustafa M. ^{[4
,5
,6
]}

机构：

[1] Univ Agr Faisalabad, Organometall & Coordinat Chem Lab, Punjab 38040, Pakistan

[2] Univ Al Muthanna, Dept Chem, Coll Sci, Samawah, Iraq

[3] Univ Agr Faisalabad, Dept Chem, Punjab 38040, Pakistan

[4] Kut Univ Coll, Dept Dent, Kut 52001, Wasit, Iraq

[5] Islamic Univ, Coll Dent, Kufa 54001, Najaf, Iraq

[6] Osol Aldeen Univ Coll, Pharm Dept, Baghdad, Iraq

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2022年 / 1250卷

关键词：

Zirconium; Synthesis; Organometallic complexes; Zirconocene; Pentalene; Catalytic applications; Polymerization; TRANSITION-METAL-COMPLEXES; METALLOCENE POLYMERIZATION CATALYSTS; RING-OPENING POLYMERIZATION; ZIEGLER-NATTA CATALYSIS; SINGLE-SITE CATALYSTS; TUCK-IN COMPLEX; C-H BOND; ETHYLENE POLYMERIZATION; OLEFIN POLYMERIZATION; ORGANOMETALLIC CHEMISTRY;

D O I：

10.1016/j.molstruc.2021.131925

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Due to the increasing demand for polymers, selecting an appropriate catalytic system is essential to achieve desirable properties in the resulting polymers, which encouraged us to compile this review. The review deals with various strategies for synthesising organometallic complexes of zirconium involving bonding through carbon and their catalytic applications in homo-and heterogeneous polymerization of olefins and lactides, spanning 2011 to 2019. We classified these complexes into three categories, i.e. ansa -type zirconocenes. Non-bridged zirconocenes and pentalene complexes. These zirconium complexes have been synthesized under an inert atmosphere by treating zirconium precursors with suitable ligands at a particular temperature, choosing appropriate solvents. (c) 2021 Elsevier B.V. All rights reserved.

引用

页数：19

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