Synthesis and characterization of a new organically templated zincophosphate:: (C2N2H10)2[Zn(PO4)2]

被引：3
作者：
Mao, Shao-Yu [1 ]
Xie, Yu [1 ]
Xie, Zhao-Xiong [1 ]
Zhao, Jing-Tai [2 ]
机构：
[1] Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2008年 / 456卷 / 1-2期
关键词：
zincophosphate; templates; crystal structure;
D O I：
10.1016/j.jallcom.2007.07.027
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Anew open-framework zincophosphate, (C2N2H10)(2)[Zn(PO4)(2)], has been synthesized hydrothermally from a mixture of zinc chloride, phosphoric acid, ethylenediamine and deionized water. It has the following crystal data: orthorhombic space group Pccn, a = 17.056(3) angstrom, b = 8.4219(17) angstrom, c = 8.7260(18) angstrom, V= 1253.4(4) angstrom(3), Z = 4. The crystal structure of the title compound is characterized by corner-sharing PO4 and ZnO4 tetrahedra, leading to infinite corner-shared four-membered ring chains. There is extensive Zn-O-P bonding in the structure in the form of infinite chains. The structure is stabilized by template-to-framework hydrogen bonding. The title compound was also characterized by IR spectroscopy and TG-DTA. Luminescent measurement of (C2N2H10)(2)[Zn(PO4)(2)] shows an emission band between 665 nm and 688 nm when excited with 451 nm UV light. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：524 / 527
页数：4
相关论文
共 50 条
[31]   Phase and melting relationships of β, α and α′-Ca3(PO4)2 polymorphs in the Ca3(PO4)2-Zn3(PO4)2 system [J].
Carbajal, Leticia ;
Serena, Sara ;
Antonia Sainz, Maria ;
Caballero, Angel .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2017, 37 (05) :2277-2283
[32]   Synthesis and Characterization of a New Layered Gallium Phosphonate Oxalate [C2H10N2]0.5[Ga3(PO3CH3)4(C2O4)].H2O [J].
Dardar, F. ;
Day, C. S. ;
El Jazouli, A. ;
Sebti, S. ;
Lachgar, A. .
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2019, 49 (01) :44-51
[33]   Ni2Sr(PO4)2•2H2O [J].
Assani, Abderrazzak ;
Saadi, Mohamed ;
Zriouil, Mohammed ;
El Ammari, Lahcen .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :I86-U206
[34]   Synthesis, structure and characterization of two new silver-iron based phosphates AgFe2(PO4)2F(H2O)2 and Ag3Fe2(PO4)(HPO4)3 [J].
Li, Ningxia ;
Luo, Qi ;
Cui, Meiyan ;
Zhao, Zhiying ;
He, Zhangzhen .
JOURNAL OF SOLID STATE CHEMISTRY, 2024, 338
[35]   Synthesis and characterization of new strontium iron (II) phosphates, SrFe2 (PO4)2 and Sr9Fe1.5 (PO4)7 [J].
Belik, AA ;
Lazoryak, BI ;
Pokholok, KV ;
Terekhina, TP ;
Leonidov, IA ;
Mitberg, EB ;
Karelina, VV ;
Kellerman, DG .
JOURNAL OF SOLID STATE CHEMISTRY, 2001, 162 (01) :113-121
[36]   Hydrothermal synthesis and structural characterization of an organically-templated zincophosphite:: [C4N2H12]0.5 • [Zn3(HPO3)4] • H3O [J].
Dong, WJ ;
Li, GH ;
Shi, Z ;
Fu, WS ;
Zhang, D ;
Chen, XB ;
Dai, ZM ;
Wang, L ;
Feng, SH .
INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (06) :776-780
[37]   New Noncentrosymmetric Tellurite Phosphate Material: Synthesis, Characterization, and Calculations of Te2O(PO4)2 [J].
Kim, Min Kyung ;
Kim, Sang-Hwan ;
Chang, Hong-Young ;
Halasyamani, P. Shiv ;
Ok, Kang Min .
INORGANIC CHEMISTRY, 2010, 49 (15) :7028-7034
[38]   Na2BaMg（PO4）2:synthesis,crystalstructureandeuropiumphotoluminescenceproperties [J].
Amal Boukhris ;
Mourad Hidouri ;
Benoit Glorieux ;
Mongi Ben Amara .
JournalofRareEarths, 2013, 31 (09) :849-856
[39]   Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence [J].
Li, Xiao-Bao ;
Hu, Chun-Li ;
Kong, Fang ;
Mao, Jiang-Gao .
INORGANIC CHEMISTRY, 2021, 60 (03) :1957-1964
[40]   SYNTHESIS, CRYSTAL STRUCTURE, AND CHARACTERIZATION OF A NEW ADDUCT 3-AMMONIUMPHENYL SULFONE DIHYDROGENPHOSPHATE PHOSPHORIC ACID [C12H14N2SO2](H2PO4)2H3PO4 [J].
Mahroug, Adel ;
Belhouchet, Mohamed ;
Hemon-Ribaud, Annie ;
Mhiri, Tahar .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2011, 186 (12) :2332-2340
12345