Synthesis and characterization of a new organically templated zincophosphate:: (C2N2H10)2[Zn(PO4)2]

被引：3
|
作者：
Mao, Shao-Yu [1 ]
Xie, Yu [1 ]
Xie, Zhao-Xiong [1 ]
Zhao, Jing-Tai [2 ]
机构：
[1] Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2008年 / 456卷 / 1-2期
关键词：
zincophosphate; templates; crystal structure;
D O I：
10.1016/j.jallcom.2007.07.027
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Anew open-framework zincophosphate, (C2N2H10)(2)[Zn(PO4)(2)], has been synthesized hydrothermally from a mixture of zinc chloride, phosphoric acid, ethylenediamine and deionized water. It has the following crystal data: orthorhombic space group Pccn, a = 17.056(3) angstrom, b = 8.4219(17) angstrom, c = 8.7260(18) angstrom, V= 1253.4(4) angstrom(3), Z = 4. The crystal structure of the title compound is characterized by corner-sharing PO4 and ZnO4 tetrahedra, leading to infinite corner-shared four-membered ring chains. There is extensive Zn-O-P bonding in the structure in the form of infinite chains. The structure is stabilized by template-to-framework hydrogen bonding. The title compound was also characterized by IR spectroscopy and TG-DTA. Luminescent measurement of (C2N2H10)(2)[Zn(PO4)(2)] shows an emission band between 665 nm and 688 nm when excited with 451 nm UV light. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：524 / 527
页数：4
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