General and Simple Method for the Synthesis of 3-nitroformazan Using Arenediazonium Tosylates

被引：3

作者：

Petunin, Pavel V. ^{[1
]}

Valiev, Rashid R. ^{[3
,4
]}

Kalinin, Rodion G. ^{[2
]}

Trusova, Marina E. ^{[1
]}

Zhdankin, Viktor V. ^{[2
]}

Postnikov, Pavel S. ^{[2
]}

机构：

[1] Tomsk Polytech Univ, Dept Biotechnol & Organ Chem, Tomsk, Russia

[2] Tomsk Polytech Univ, Dept Technol Organ Subst & Polymer Mat, Tomsk, Russia

[3] Tomsk Polytech Univ, Dept Gen & Inorgan Chem, Tomsk, Russia

[4] Tomsk State Univ, Dept Opt & Spect, Tomsk, Russia

来源：

CURRENT ORGANIC SYNTHESIS | 2016年 / 13卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

Arenediazonium tosylates; azo-coupling; diazonium salts; formazans; quantum-chemical calculations; TDDFT; FORMAZANS; TETRAPHENYLPORPHYRIN; SALTS;

D O I：

10.2174/1570179413666160205002843

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general and simple procedure for the synthesis of 3-nitroformazan using arenediazonium tosylates was developed. This convenient procedure can be applied for the preparation of 3-nitroformazans containing electron-donating or electron-withdrawing groups. First the anomaly 1,5-bis(4-methoxyphenyl)-3-nitroformazan was synthesized as the mixture of TSSC (trans-syn, s-cis) and previously unknown for 3-nitroformazans TASC (transanti, s-cis) isomers. The structure and spectral characteristics of TASC isomer were explained using quantum-chemical calculation with TDDFT/B3LYP/6-31++ G(d,p) level of theory.

引用

页码：623 / 628

页数：6

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