Lithium ion conduction in LiTi2(PO4)3

被引：90

作者：

Takada, K ^{[1
]}

Tansho, M ^{[1
]}

Yanase, I ^{[1
]}

Inada, T ^{[1
]}

Kajiyama, A ^{[1
]}

Kouguchi, M ^{[1
]}

Kondo, S ^{[1
]}

Watanabe, M ^{[1
]}

机构：

[1] Natl Inst Res Inorgan Mat, Tsukuba, Ibaraki 3050044, Japan

来源：

SOLID STATE IONICS | 2001年 / 139卷 / 3-4期

基金：

日本科学技术振兴机构;

关键词：

lithium titanium phosphate; glassy electrolyte; lithium ion conductor;

D O I：

10.1016/S0167-2738(01)00688-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Li+ ion conduction was examined for a mixture of LiTi2(PO4)(3) (LTP) and a glassy electrolyte. 0.01Li(3)PO(4)-0.63Li(2)S-0.36SiS(2). The addition of LTP with 10 wt.% resulted in a significant decrease in activation energy for conduction and little influence on the Lif ion conductivity, although it reduced the conduction path in the glass. The Li-7 NMR spectra of LTP was quite similar to that of Li1.3Al0.3Ti1.7(PO4)(3) (LATP) with a high conductivity of 10(-3) S cm(-1). These results suggest that Li+ ion conduction in LTP is as high as that in the glassy electrolyte and LATP. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：241 / 247

页数：7

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