Recognition of anions using metalloporphyrin-based ion-selective membranes:: State-of-the-art

被引：60
作者：
Górski, L
Malinowska, E
Parzuchowski, P
Zhang, W
Meyerhoff, ME
机构：
[1] Tech Univ Warsaw, Fac Chem, PL-00664 Warsaw, Poland
[2] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
来源：
ELECTROANALYSIS | 2003年 / 15卷 / 15-16期
关键词：
metalloporphyrins; anion-selective membranes; dimer-monomer equilibrium; potentiometric sensors; optical sensors; DIMER-MONOMER EQUILIBRIUM; INDIUM(III) OCTAETHYLPORPHYRIN; POLYMERIC MEMBRANES; ELECTRODES; IONOPHORES; PORPHYRIN; SENSOR;
D O I：
10.1002/elan.200302814
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The principles, recent achievements and challenges related to the use of metalloporphyrins as ionophores in the development of polymeric anion-selective membranes are reported. The advantages and disadvantages of dimer-monomer equilibria existing within the membrane phase when using certain metalloporphyrins are discussed with respect to their effect on the response characteristics of the resulting anion sensors. The influence of membrane composition and pH of sample solution on these equilibria is described. The possibility of employing both potentiometric and optical transduction modes for anion recognition with metalloporphyrin doped polymer membranes is shown.
引用
收藏
页码：1229 / 1235
页数：7
相关论文
共 28 条
[1]   ANION SELECTIVITY OF METALLOPORPHYRINS IN MEMBRANES [J].
AMMANN, D ;
HUSER, M ;
KRAUTLER, B ;
RUSTERHOLZ, B ;
SCHULTHESS, P ;
LINDEMANN, B ;
HALDER, E ;
SIMON, W .
HELVETICA CHIMICA ACTA, 1986, 69 (04) :849-854
[2]   ANION-SELECTIVE MEMBRANE ELECTRODES BASED ON METALLOPORPHYRINS - THE INFLUENCE OF LIPOPHILIC ANIONIC AND CATIONIC SITES ON POTENTIOMETRIC SELECTIVITY [J].
BAKKER, E ;
MALINOWSKA, E ;
SCHILLER, RD ;
MEYERHOFF, ME .
TALANTA, 1994, 41 (06) :881-890
[3]   Selectivity of potentiometric ion sensors [J].
Bakker, E ;
Pretsch, E ;
Bühlmann, P .
ANALYTICAL CHEMISTRY, 2000, 72 (06) :1127-1133
[4]   Carrier-based ion-selective electrodes and bulk optodes. 2. Ionophores for potentiometric and optical sensors [J].
Buhlmann, P ;
Pretsch, E ;
Bakker, E .
CHEMICAL REVIEWS, 1998, 98 (04) :1593-1687
[5]   MEMBRANE-DIALYZER INJECTION LOOP FOR ENHANCING THE SELECTIVITY OF ANION-RESPONSIVE LIQUID-MEMBRANE ELECTRODES IN FLOW SYSTEMS .2. A SELECTIVE SENSING SYSTEM FOR SALICYLATE [J].
CHANG, Q ;
MEYERHOFF, ME .
ANALYTICA CHIMICA ACTA, 1986, 186 :81-90
[6]   SALICYLATE-SELECTIVE MEMBRANE-ELECTRODE BASED ON TIN(IV) TETRAPHENYLPORPHYRIN [J].
CHANIOTAKIS, NA ;
PARK, SB ;
MEYERHOFF, ME .
ANALYTICAL CHEMISTRY, 1989, 61 (06) :566-570
[7]   A nearly linear single hydroxo bridge. Synthesis, structure, and magnetic susceptibility of (mu-hydroxo)bis((tetraphenylporphinato)manganese(III)) perchlorate [J].
Cheng, BS ;
Fries, PH ;
Marchon, JC ;
Scheidt, WR .
INORGANIC CHEMISTRY, 1996, 35 (04) :1024-1032
[8]   A NOVEL DIMANGANESE(III) COMPLEX WITH A SINGLE HYDROXO BRIDGE - SYNTHESES, STRUCTURES, AND MAGNETIC-SUSCEPTIBILITIES OF (MU-HYDROXO)BIS((OCTAETHYLPORPHINATO)MANGANESE(III)) PERCHLORATE AND A MONOMERIC PRECURSOR, AQUO(OCTAETHYLPORPHINATO)MANGANESE(III) PERCHLORATE [J].
CHENG, BS ;
CUKIERNIK, F ;
FRIES, PH ;
MARCHON, JC ;
SCHEIDT, WR .
INORGANIC CHEMISTRY, 1995, 34 (18) :4627-4639
[9]   ANION-SELECTIVE ELECTRODES BASED ON ELECTROPOLYMERIZED PORPHYRIN FILMS [J].
DAUNERT, S ;
WALLACE, S ;
FLORIDO, A ;
BACHAS, LG .
ANALYTICAL CHEMISTRY, 1991, 63 (17) :1676-1679
[10]  
Dolphin D., 1978, PORPHYRINS, V5
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