Investigations of red mud as a catalyst in Mahua oil biodiesel production and its engine performance

被引:36
作者
Senthil, M. [1 ]
Visagavel, K. [1 ]
Saravanan, C. G. [2 ]
Rajendran, Karthik [3 ,4 ]
机构
[1] Knowledge Inst Technol, Dept Mech Engn, Salem, India
[2] Annamalai Univ, Dept Mech Engn, Chidambaram, India
[3] Univ Hawaii Manoa, Dept Mol Biosci & Bioengn, Honolulu, HI 96822 USA
[4] Veltech Dr RR & Dr SR Tech Univ, Reg Biorefinery Lab RBL, Madras 600062, Tamil Nadu, India
关键词
Biodiesel; Diesel engine; Engine performance; Blending; Red mud; Characterization; PYROLYSIS;
D O I
10.1016/j.fuproc.2016.03.027
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Biodiesel productions from Mahua oil using two different catalysts, including KOH and activated red mud by catalytic cracking (waste from aluminum industry) were compared in distinctive blends of diesel fuel. Red mud was subjected to characterization studies to find the mechanism of red mud during catalytic cracking using Energy Dispersive Spectroscopy (EDS) and Scanning Electron Microscope (SEM). The cracking process was carried at 300 degrees C for 2 h and different blends of biodiesel (B25, B50, B75, and B100) were examined for physical properties. Furthermore, the different blends were subjected to a four-stroke diesel engine to study its engine performance. The results showed that the changes in elemental composition during EDS analysis could be an important reason for red mud to have a better calorific value (10,601 kcal/kg) compared to KOH as a catalyst The NOx emission from KOH biodiesel was 7.5% higher compared to red mud biodiesel when it was blended 100% at 1500 RPM at a maximum brake power (52 kW). From the findings of this study, it was evident that using red mud as a catalyst not just increases most of the properties of the fuel, but also reduces the stress on the environment in the form of less emission and fuel consumption. Since red mud was a hazardous waste from aluminum industry, utilizing it for biodiesel productions could also be an economically viable option. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:7 / 14
页数:8
相关论文
共 23 条
[1]   Non-edible vegetable oils: A critical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engine performance and emissions production [J].
Atabani, A. E. ;
Silitonga, A. S. ;
Ong, H. C. ;
Mahlia, T. M. I. ;
Masjuki, H. H. ;
Badruddin, Irfan Anjum ;
Fayaz, H. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2013, 18 :211-245
[2]   The effects of catalysts in biodiesel production: A review [J].
Atadashi, I. M. ;
Aroua, M. K. ;
Aziz, A. R. Abdul ;
Sulaiman, N. M. N. .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2013, 19 (01) :14-26
[3]   Waste materials - catalytic opportunities: an overview of the application of large scale waste materials as resources for catalytic applications [J].
Balakrishnan, M. ;
Batra, V. S. ;
Hargreaves, J. S. J. ;
Pulford, I. D. .
GREEN CHEMISTRY, 2011, 13 (01) :16-24
[4]   Effects of biodiesel on a DI diesel engine performance, emission and combustion characteristics [J].
Buyukkaya, Ekrem .
FUEL, 2010, 89 (10) :3099-3105
[5]   Combustion analysis of preheated crude sunflower oil in an IDI diesel engine [J].
Canakci, Mustafa ;
Ozsezen, Ahmet Necati ;
Turkcan, Ali .
BIOMASS & BIOENERGY, 2009, 33 (05) :760-767
[6]   Competitive liquid biofuels from biomass [J].
Demirbas, Ayhan .
APPLIED ENERGY, 2011, 88 (01) :17-28
[7]   Performance, emission and combustion characteristics of poon oil and its diesel blends in a DI diesel engine [J].
Devan, P. K. ;
Mahalakshmi, N. V. .
FUEL, 2009, 88 (05) :861-867
[8]  
International Energy Agency, 2014, PRIM EN CONS
[9]  
International Energy Statistics, 2014, EN PROD COUNTR
[10]   Red Mud as a Catalyst for the Upgrading of Hemp-Seed Pyrolysis Bio-oil [J].
Karimi, Elham ;
Briens, Cedric ;
Berruti, Franco ;
Moloodi, Sina ;
Tzanetakis, Tommy ;
Thomson, Murray J. ;
Schlaf, Marcel .
ENERGY & FUELS, 2010, 24 (12) :6586-6600