Solvent extraction of heavy lanthanides(III) with 5,7-dibromo-8-hydroxyquinoline from aqueous perchlorate solution

被引:13
作者
Czakis-Sulikowska, D [1 ]
Pustelnik, N [1 ]
机构
[1] Tech Univ Lodz, Inst Gen & Ecol Chem, PL-90924 Lodz, Poland
关键词
solvent extraction; lanthanides(III); 5,7-dibromo-8-hydroxyquinoline;
D O I
10.1081/SEI-120024555
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The extraction of Tb(III), Dy(III), Ho(III), Er(III), Tm(III), and Yb(III) with 5,7-dibromo-8-hydroxyquinoline (Hdbq or HA) in chloroform from aqueous perchlorate solutions was investigated. The formation of the LnA(3) species (where Ln=Tb, Dy, Ho, Er, Tm, and Yb) in the organic phase was supported by the data. The parameters of the extraction processes were determined, and the separation factors between two adjacent lanthanides(III) were calculated.
引用
收藏
页码:751 / 762
页数:12
相关论文
共 25 条
[1]   SOLVENT-EXTRACTION OF RARE-EARTH METAL-IONS WITH THENOYLTRIFLUOROACETONE IN CARBON-TETRACHLORIDE [J].
ALSTAD, J ;
AUGUSTSON, JH ;
FARBU, L .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1974, 36 (04) :899-903
[2]  
Czakis-Sulikowska D, 2001, CHEM ANAL-WARSAW, V46, P93
[3]  
Czakis-Sulikowska D, 1999, CHEM ANAL-WARSAW, V44, P925
[4]   Extraction studies on the formation of La(III), Gd(III) and Lu(III) species with 5,7-dihalogeno derivatives of 8-hydroxyquinoline [J].
Czakis-Sulikowska, D ;
Pustelnik, N ;
Kuznik, B ;
Malinowska, A .
JOURNAL OF ALLOYS AND COMPOUNDS, 2000, 300 :234-237
[5]  
CzakisSulikowska D, 1997, CHEM ANAL-WARSAW, V42, P23
[6]  
CZAKISSULIKOWSKA D, 1993, CHEM ANAL-WARSAW, V38, P53
[7]   ROLE OF THE INTERFACE IN THE KINETICS AND MECHANISM OF NICKEL EXTRACTION WITH CERTAIN HALOGEN-SUBSTITUTED AND ALKYL-SUBSTITUTED 8-QUINOLINOLS [J].
DIETZ, ML ;
FREISER, H .
LANGMUIR, 1991, 7 (02) :284-288
[8]   STUDIES ON THE EXTRACTION OF METAL COMPLEXES .31. INVESTIGATIONS WITH SOME 5,7-DIHALOGEN DERIVATIVES OF 8-QUINOLINOL [J].
DYRSSEN, D ;
DYRSSEN, M ;
JOHANSSON, E .
ACTA CHEMICA SCANDINAVICA, 1956, 10 (03) :341-352
[10]   MIXED-LIGAND CHELATE EXTRACTION OF LANTHANIDES WITH 5,7-DIBROMO-8-QUINOLINOL AND 4,4'-(5-NONYL)-2,2'-DIPYRIDYLAMINE SYSTEMS [J].
FUJINAGA, K ;
HOJJATIE, M ;
FREISER, H .
ANALYTICAL SCIENCES, 1988, 4 (02) :139-142