Growth and characterization of air annealing Tb-doped YAG:Ce single crystal for white-light-emitting diode

被引:29
作者
Gong, Maogao [1 ]
Xiang, Weidong [1 ]
Liang, Xiaojuan [1 ]
Zhong, Jiasong [2 ]
Chen, Daqin [2 ]
Huang, Jun [1 ]
Gu, Guorui [1 ]
Yang, Cheng [1 ]
Xiang, Run [1 ]
机构
[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China
[2] Hangzhou Dianzi Univ, Coll Mat & Environm Engn, Hangzhou 310018, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
White LED; Crystal growth; X-ray powder diffractometer; Optical properties; ENERGY-TRANSFER; PHOSPHOR; LUMINESCENCE; TEMPERATURE; CERAMICS; CEYAG; CR;
D O I
10.1016/j.jallcom.2015.03.162
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the preparation of transparent Ce and Tb co-doped Y3Al5O12 single crystal by the Czochralski method. The characterization of the resulting single crystal was accomplished by using X-ray powder diffractometer, scanning electron microscopy and energy dispersive X-ray spectroscopy. Absorption peak of the single crystal at about 460 nm has been obtained from ultraviolet-visible absorption spectrometer and their intensity is changed with different annealing condition. Its optical properties also have been investigated using fluorescence spectrometer. What's more, its photoelectric parameters were studied by LED fast spectrometer. The constructed single crystal based white-light-emitting diode exhibits a high luminous efficiency of 140.89 lm/W, and a correlated color temperature of 4176 K as well as a color rendering index of 56.7, which reveal the prominent feasibility of the present single crystal material in white-light-emitting diode application. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:611 / 616
页数:6
相关论文
共 45 条
[1]   Luminescence and energy transfer of Eu3+ or/and Dy3+ co-doped in Sr3AlO4F phosphors with NUV excitation for WLEDs [J].
Bandi, Vengala Rao ;
Grandhe, Bhaskar Kumar ;
Woo, Hyun-Joo ;
Jang, Kiwan ;
Shin, Dong-Soo ;
Yi, Soung-Soo ;
Jeong, Jung-Hyun .
JOURNAL OF ALLOYS AND COMPOUNDS, 2012, 538 :85-90
[2]  
Bando K., 1998, J LIGHT VIS ENVIRON, V22, P2, DOI [DOI 10.2150/JLVE.22.12, 10.2150/jlve.22.1_2, DOI 10.2150/JLVE.22.1_2]
[3]   Temperature and concentration quenching of Tb3+ emissions in Y4Al2O9 crystals [J].
Boruc, Z. ;
Fetlinski, B. ;
Kaczkan, M. ;
Turczynski, S. ;
Pawlak, D. ;
Malinowski, M. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2012, 532 :92-97
[4]   Lanthanide-activated Na5Gd9F32 nanocrystals precipitated from a borosilicate glass: Phase-separation-controlled crystallization and optical property [J].
Chen, Daqin ;
Wan, Zhongyi ;
Zhou, Yang ;
Chen, Yan ;
Yu, Hua ;
Lu, Hongwei ;
Ji, Zhenguo ;
Huang, Ping .
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 625 :149-157
[5]   Eu2+/Sm3+ ions co-doped white light luminescence SrSiO3 glass-ceramics phosphor for White LED [J].
Cui, Zhiguang ;
Ye, Renguang ;
Deng, Degang ;
Hua, Youjie ;
Zhao, Shilong ;
Jia, Guohua ;
Li, Chenxia ;
Xu, Shiqing .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (08) :3553-3558
[6]   High luminance LEDs replace incandescent lamps in new applications [J].
Evans, DL .
LIGHT-EMITTING DIODES: RESEARCH, MANUFACTURING, AND APPLICATIONS, 1997, 3002 :142-153
[7]   Preparation of Y3Al5O12:Cr powders by microwave-induced combustion process and their luminescent properties [J].
Fu, YP ;
Tsao, S ;
Hu, CT .
JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 395 (1-2) :227-230
[8]  
Fujita S., 2005, P SOC PHOTO-OPT INS, V5941
[9]   Blue-emitting phosphor M2B5O9Cl Eu2+ (M=Sr, Ca) for white LEDs [J].
Guo, Chongfeng ;
Xu, Yan ;
Ding, Xu ;
Li, Ming ;
Yu, Jie ;
Ren, Zhaoyu ;
Bai, Jintao .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (04) :L38-L41
[10]   Yttrium antisite reduction and improved photodiode performance in Ce doped Y3Al5O12 by Czochralski growth in alumina rich melts [J].
Haven, Drew T. ;
Dickens, Peter T. ;
Weber, Marc H. ;
Lynn, Kelvin G. .
JOURNAL OF APPLIED PHYSICS, 2013, 114 (04)