机构:
Indian Assoc Cultivat Sci, Dept Mat Sci, Jadavpur 700032, Kolkata, IndiaIndian Assoc Cultivat Sci, Dept Mat Sci, Jadavpur 700032, Kolkata, India
Bhaumik, A
[1
]
Mal, NY
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机构:Indian Assoc Cultivat Sci, Dept Mat Sci, Jadavpur 700032, Kolkata, India
Mal, NY
机构:
[1] Indian Assoc Cultivat Sci, Dept Mat Sci, Jadavpur 700032, Kolkata, India
[2] Natl Inst Adv Ind Sci & Technol, Dynam Mat Res Grp, Kansai Ctr, Ikeda, Osaka 5638577, Japan
来源:
SCIENCE AND TECHNOLOGY IN CATALYSIS 2002
|
2003年
/
145卷
关键词:
D O I:
10.1016/S0167-2991(03)80200-8
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
A new microporous zinc silicate ZS-1 with Si to Zn mole ratio in the range 5.2 to 11.4 have been synthesized under hydrothermal condition using dibutyl amine as structure directing agent (SDA) in the presence of H3PO4 promoter. SDA can be removed by acid / ethanol extraction and the material show microporosity in N-2 sorption measurement. This material show very strong surface acidity and practically no loss of zinc on heating the acid extracted sample at 773 K for 6h.