A novel polymer quaternary ammonium iodide and application in quasi-solid-state dye-sensitized solar cells

被引:33
作者
Li, WY [1 ]
Kang, JJ [1 ]
Li, XP [1 ]
Fang, SB [1 ]
Lin, Y [1 ]
Wang, GQ [1 ]
Xiao, XR [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Key Lab Photochem, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
polymer electrolyte; polymer quaternary ammonium iodide; polyacrylonitrile; ionic conductivity; quasi-solid-state dye-sensitized solar cells;
D O I
10.1016/j.jphotochem.2004.07.016
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The characteristics of electrolytes containing novel polymer quaternary ammonium iodide, polysiloxane with quaternary ammonium side groups (PSQAS), were investigated. PSQAS exhibits a single-anionic conductivity and has special advantages over usually used iodides in dye-sensitized solar cells. Electrolytes based on PSQAS exhibited the maximum ambient conductivity (25 degreesC of 4.96 x 10(-3) S cm(-1). The polymer gel electrolyte based on PAN and PSQAS has been employed to fabricate quasi-solid- state dye-sensitized solar cell with an overall conversion efficiency of 2.67% at irradiation of 100 mW cm(-2). (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 6
页数:6
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