Conductive polyaniline-polychloroprene blends

被引：0
作者：
Pinho, MS
Gorelova, MM
Dezzoti, M
Soares, BG
Pertsin, AJ
机构：
[1] Univ Fed Rio de Janeiro, Inst Macromol, Ctr Tecnol, BR-21945970 Rio De Janeiro, Brazil
[2] Russian Acad Sci, Inst Organoelement Cpds, Moscow 117813, Russia
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 1998年 / 70卷 / 08期
关键词：
polychloroprene; polyaniline; conductive blends;
D O I：
10.1002/(SICI)1097-4628(19981121)70:8<1543::AID-APP11>3.0.CO;2-F
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The electrical conductivity of polychloroprene (CR)/polyaniline (Pani) blends prepared by bulk and solution processes were investigated. Pani doped with HCl (Pani . HCl) and p-toluenesulfonic acid (Pani . TSA) were employed in vulcanized blends obtained by the bulk process. These blends showed an increase in the conductivity only for blend composition of CR/Pani = 50:50 wt %. At this composition, blends with Pani HCl and Pani . pTSA presented conductivity values of 10(-9) and 10(-10) S . cm(-1) respectively. CR/Pani . HCl blend films prepared by the solution process displayed surface conductivity values of 10(-4) S . cm(-1) with as low as 10-15 wt % of PAni . HCl. Surface analysis of these blends by X-ray photoelectron spectroscopy indicated no traces of the conductive additive. The surface composition was found to be exclusively constituted of CR. (C) 1998 John Wiley & Sons, Inc.
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页码：1543 / 1549
页数：7
相关论文
共 17 条
[1]   Low temperature synthesis of high molecular weight polyaniline [J].
Adams, PN ;
Laughlin, PJ ;
Monkman, AP ;
Kenwright, AM .
POLYMER, 1996, 37 (15) :3411-3417
[2]  
ASTURIAS GE, 1989, SYNTHETIC MET, V29, pE157
[3]   POLYANILINE PLASTICIZED WITH 1-METHYL-2-PYRROLIDONE - STRUCTURE AND DOPING BEHAVIOR [J].
CHEN, SA ;
LEE, HT .
MACROMOLECULES, 1993, 26 (13) :3254-3261
[4]   PROCESSABLE FORMS OF CONDUCTIVE POLYANILINE [J].
DAVIES, SJ ;
RYAN, TG ;
WILDE, CJ ;
BEYER, G .
SYNTHETIC METALS, 1995, 69 (1-3) :209-210
[5]   COUNTERION INDUCED PROCESSIBILITY OF POLYANILINE - CONDUCTING MELT PROCESSIBLE POLYMER BLENDS [J].
IKKALA, OT ;
LAAKSO, J ;
VAKIPARTA, K ;
VIRTANEN, E ;
RUOHONEN, H ;
JARVINEN, H ;
TAKA, T ;
PASSINIEMI, P ;
OSTERHOLM, JE ;
CAO, Y ;
ANDREATTA, A ;
SMITH, P ;
HEEGER, AJ .
SYNTHETIC METALS, 1995, 69 (1-3) :97-100
[6]   X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF H2SO4 PROTONATED POLYANILINE [J].
KANG, ET ;
NEOH, KG ;
WOO, YL ;
TAN, KL .
POLYMER, 1992, 33 (13) :2857-2859
[7]  
Kim S, 1996, POLYM ADVAN TECHNOL, V7, P599, DOI 10.1002/(SICI)1099-1581(199607)7:7<599::AID-PAT549>3.3.CO
[8]  
2-F
[9]   PROPERTIES OF ELECTRONICALLY CONDUCTIVE POLYANILINE - A COMPARISON BETWEEN WELL-KNOWN LITERATURE DATA AND SOME RECENT EXPERIMENTAL FINDINGS [J].
LUX, F .
POLYMER, 1994, 35 (14) :2915-2936
[10]   PROTONATION OF POLYANILINE FILMS - EFFECTS OF ANION SIZE AND FILM STRUCTURE [J].
NEOH, KG ;
KANG, ET ;
TAN, KL .
POLYMER, 1994, 35 (13) :2899-2901
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