共 44 条
A novel porous flower-like HA/Ag nanocomposite: One pot preparation and excellent performances as both SERS nanosensor and catalyst
被引:9
作者:
Gao, Xinna
[1
]
Wu, Yun
[1
]
Huang, Yiping
[1
]
Yang, Ying
[1
]
Xie, Anjian
[1
]
Shen, Yuhua
[1
]
机构:
[1] Anhui Univ, Sch Chem & Chem Engn, Hefei, Anhui, Peoples R China
关键词:
Surface enhanced Raman scattering;
Flower-like HA/Ag nanocomposite;
Detection;
Catalyst;
Porous structure;
ENHANCED RAMAN-SPECTROSCOPY;
PHOTOCATALYTIC DEGRADATION;
AG-NANOPARTICLES;
MAGNETIC NANOPARTICLES;
EFFICIENT CATALYST;
SURFACE LIGANDS;
REDUCTION;
GOLD;
HYDROGENATION;
SUBSTRATE;
D O I:
10.1016/j.micromeso.2017.08.042
中图分类号:
O69 [应用化学];
学科分类号:
081704 ;
摘要:
Surface enhanced Raman scattering (SERS) as a powerful analytical tool provides strong enhancement factors, good reproducibility and stability, which has gained good application effect. But single-use or single functional SERS substrate has been limited to the needs of the people. Here, a porous flower-like Hydroxyapatite (HA)/Ag nanocomposite was prepared via one-pot sol-thermal method without any templates. The unique Raman enhancement effect of the HA/Ag nanocomposite as the SERS-active substrate was revealed by the rhodamine 6G (Rh6G) detection at a concentration as low as 1 x 10(-10) M. In addition, the as-prepared porous nanocomposite as the catalyst for the reduction of p-nitrophenol (4-NP) can greatly shorten reaction time to 8 min (The rate constant k of the catalytic reaction is 0.426 min(-1)). Thus, the HA/Ag nanocomposite has wide applications in environmental detection and efficient catalytic degradation for organic pollutants. (C) 2017 Elsevier Inc. All rights reserved.
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页码:1 / 7
页数:7
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