A novel porous flower-like HA/Ag nanocomposite: One pot preparation and excellent performances as both SERS nanosensor and catalyst

被引:9
作者
Gao, Xinna [1 ]
Wu, Yun [1 ]
Huang, Yiping [1 ]
Yang, Ying [1 ]
Xie, Anjian [1 ]
Shen, Yuhua [1 ]
机构
[1] Anhui Univ, Sch Chem & Chem Engn, Hefei, Anhui, Peoples R China
关键词
Surface enhanced Raman scattering; Flower-like HA/Ag nanocomposite; Detection; Catalyst; Porous structure; ENHANCED RAMAN-SPECTROSCOPY; PHOTOCATALYTIC DEGRADATION; AG-NANOPARTICLES; MAGNETIC NANOPARTICLES; EFFICIENT CATALYST; SURFACE LIGANDS; REDUCTION; GOLD; HYDROGENATION; SUBSTRATE;
D O I
10.1016/j.micromeso.2017.08.042
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Surface enhanced Raman scattering (SERS) as a powerful analytical tool provides strong enhancement factors, good reproducibility and stability, which has gained good application effect. But single-use or single functional SERS substrate has been limited to the needs of the people. Here, a porous flower-like Hydroxyapatite (HA)/Ag nanocomposite was prepared via one-pot sol-thermal method without any templates. The unique Raman enhancement effect of the HA/Ag nanocomposite as the SERS-active substrate was revealed by the rhodamine 6G (Rh6G) detection at a concentration as low as 1 x 10(-10) M. In addition, the as-prepared porous nanocomposite as the catalyst for the reduction of p-nitrophenol (4-NP) can greatly shorten reaction time to 8 min (The rate constant k of the catalytic reaction is 0.426 min(-1)). Thus, the HA/Ag nanocomposite has wide applications in environmental detection and efficient catalytic degradation for organic pollutants. (C) 2017 Elsevier Inc. All rights reserved.
引用
收藏
页码:1 / 7
页数:7
相关论文
共 44 条
[2]   Nickel Nanoparticles in Hydrogen Transfer Reactions [J].
Alonso, Francisco ;
Riente, Paola ;
Yus, Miguel .
ACCOUNTS OF CHEMICAL RESEARCH, 2011, 44 (05) :379-391
[3]   SERS detection of environmental pollutants in humic acid-gold nanoparticle composite materials [J].
Alvarez-Puebla, Ramon A. ;
dos Santos, David S., Jr. ;
Aroca, Ricardo F. .
ANALYST, 2007, 132 (12) :1210-1214
[4]   Traps and cages for universal SERS detection [J].
Alvarez-Puebla, Ramon A. ;
Liz-Marzan, Luis M. .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (01) :43-51
[5]   SERS-Based Diagnosis and Biodetection [J].
Alvarez-Puebla, Ramon A. ;
Liz-Marzan, Luis M. .
SMALL, 2010, 6 (05) :604-610
[6]   Correlation between catalytic activity and surface ligands of monolayer protected gold nanoparticles [J].
Biswas, Mrinmoy ;
Dinda, Enakshi ;
Rashid, Md. Harunar ;
Mandal, Tarun K. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 368 :77-85
[7]   Photocatalytic degradation of model textile dyes in wastewater using ZnO as semiconductor catalyst [J].
Chakrabarti, S ;
Dutta, BK .
JOURNAL OF HAZARDOUS MATERIALS, 2004, 112 (03) :269-278
[8]   Visible light induced photocatalytic degradation of organic pollutants [J].
Chatterjee, D ;
Dasgupta, S .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2005, 6 (2-3) :186-205
[9]   Ag Nanoparticle/Polydopamine-Coated Inverse Opals as Highly Efficient Catalytic Membranes [J].
Choi, Gwan H. ;
Rhee, Do Kyung ;
Park, A. Reum ;
Oh, Min Jun ;
Hong, Sunhwan ;
Richardson, Joseph J. ;
Guo, Junling ;
Caruso, Frank ;
Yoo, Pil J. .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (05) :3250-3257
[10]   Surface-enhanced Raman spectroscopy (SERS): progress and trends [J].
Cialla, Dana ;
Maerz, Anne ;
Boehme, Rene ;
Theil, Frank ;
Weber, Karina ;
Schmitt, Michael ;
Popp, Juergen .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2012, 403 (01) :27-54