The yeast-mediated reduction of nitrostyrenes in organic solvent systems

被引：16

作者：

Bak, RR ^{[1
]}

McAnda, AF ^{[1
]}

Smallridge, AJ ^{[1
]}

Trewhella, MA ^{[1
]}

机构：

[1] VICTORIA UNIV TECHNOL,CTR BIOPROC & FOOD TECHNOL,MELBOURNE,VIC 8001,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1996年 / 49卷 / 11期

关键词：

D O I：

10.1071/CH9961257

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A range of nitrostyrenes have been reduced with dried baker's yeast in an organic solvent system. It was found that the reduction proceeded smoothly to give the corresponding nitroalkanes in good yield and with higher efficiency than the corresponding aqueous reaction system. No evidence for reduction of the nitro group was observed. In the case of beta-methyl nitrostyrenes, racemic mixtures were formed, and it was shown that this is not due to racemization of the product.

引用

页码：1257 / 1260

页数：4

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