Manganese oxide-catalyzed transformation of primary amines to primary amides through the sequence of oxidative dehydrogenation and successive hydration

被引：93

作者：

Wang, Ye ^{[1
]}

Kobayashi, Hiroaki ^{[1
]}

Yamaguchi, Kazuya ^{[1
]}

Mizuno, Noritaka ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 20期

关键词：

OCTAHEDRAL MOLECULAR-SIEVES; BECKMANN REARRANGEMENT; HETEROGENEOUS OXIDATION; HYDROXIDE CATALYST; ALCOHOLS; EFFICIENT; ALDOXIMES; NITRILES; OXIMES; WATER;

D O I：

10.1039/c2cc17499e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Manganese oxide octahedral molecular sieves (OMS-2) could act as an efficient, reusable heterogeneous catalyst for transformation of various primary amines to the corresponding primary amides through the sequence of oxidative dehydrogenation and successive hydration.

引用

页码：2642 / 2644

页数：3

共 7 条

[1] Manganese Oxide-catalyzed Additive- and Solvent-free Aerobic Oxidative Synthesis of Primary Amides from Primary Amines
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[4] Green oxidative synthesis of primary amides from primary alcohols or aldehydes catalyzed by a cryptomelane-type manganese oxide-based octahedral molecular sieve, OMS-2
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[7] Molecular-Iodine-Catalyzed Transformation of Benzyl Amines to N-Benzyl Benzamides via Oxidative Dehydrogenation/A2 like Self-Coupling and Hydration under Metal-Free Mild Conditions
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