Synthesis and Characterization of Polyhydroxyurethanes Prepared from Difunctional Six-Membered Ring Carbonates

被引：8
作者：
Anders, Thorsten
Keul, Helmut [1 ]
Moeller, Martin
机构：
[1] Rhein Westfal TH Aachen, DWI RWTH Aachen Ev, D-52056 Aachen, Germany
来源：
DESIGNED MONOMERS AND POLYMERS | 2011年 / 14卷 / 06期
关键词：
Carbonate coupler; functional polymers; polycondensation; poly(hydroxyl urethane); ring-opening reaction; CYCLIC CARBONATES; OPENING POLYMERIZATION; POLYADDITION; SELECTIVITY; COUPLERS; POLYMERS;
D O I：
10.1163/156855511X601592
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
New polyhydroxyurethanes (PHUs) were prepared from (5-ethyl-2-oxo-1,3-dioxan-5-yl)methyl phenyl carbonate and (5-ethyl-2-oxo-1,3-dioxan-5-yl) methyl imidazolyl carbonate with ethylenediamine, tetramethylenediamine and hexamethylenediamine. These PHUs were characterized by SEC, DSC, TGA, NMR spectroscopy and IR spectroscopy, and the results were compared to previously reported results of PHUs prepared from phenoxycarbonyl-oxymethyl ethylene carbonate with corresponding diamines. (C) Koninklijke Brill NV, Leiden, 2011
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页码：593 / 608
页数：16
相关论文
共 23 条
  • [1] *DAS DI-ISOCYANAT-POLYADDITIONSVERFAHREN (POLYURETHANE)
    BAYER, O
    [J]. ANGEWANDTE CHEMIE, 1947, 59 (09): : 257 - 272
  • [2] Synthesis and chemical recycling of a polycarbonate obtained by anionic ring-opening polymerization of a bifunctional cyclic carbonate
    Endo, T
    Kakimoto, K
    Ochiai, B
    Nagai, D
    [J]. MACROMOLECULES, 2005, 38 (20) : 8177 - 8182
  • [3] Carbonate Couplers and Functional Cyclic Carbonates from Amino Acids and Glucosamine
    Fricke, Nicole
    Keul, Helmut
    Moeller, Martin
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2009, 210 (3-4) : 242 - 255
  • [4] Gum Wilson., 1992, Reaction Polymers
  • [5] Synthesis, characterization, and application of a bifunctional coupler containing a five- and a six-membered ring carbonate
    He, Yingchun
    Keul, Helmut
    Moeller, Martin
    [J]. REACTIVE & FUNCTIONAL POLYMERS, 2011, 71 (02) : 175 - 186
  • [6] Synthesis, Characterization, and Selectivity of Bifunctional Couplers
    He, Yingchun
    Goel, Vishal
    Keul, Helmut
    Moeller, Martin
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2010, 211 (22) : 2366 - 2381
  • [7] HOVESTADT W, 1994, Patent No. 4432647
  • [8] Ionescu M., 2005, Rapra Technology
  • [9] SYNTHESIS AND PROPERTIES OF POLY(HYDROXYURETHANE)S
    KIHARA, N
    ENDO, T
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (11) : 2765 - 2773
  • [10] Matsuo J, 1998, J POLYM SCI POL CHEM, V36, P2463, DOI 10.1002/(SICI)1099-0518(199810)36:14<2463::AID-POLA4>3.0.CO
123