Copolymerization of Ethylene with Selected Vinyl Monomers Catalyzed by Group 4 Metal and Vanadium Complexes with Multidentate Ligands: A Short Review

被引：8
作者：
Bialek, Marzena [1 ]
Fryga, Julia [1 ]
机构：
[1] Univ Opole, Inst Chem, Oleska 48, PL-45052 Opole, Poland
来源：
POLYMERS | 2021年 / 13卷 / 24期
关键词：
post-metallocene catalys; copolymerization; ethylene; 1-olefin; styrenic monomer; a; -alkenol; MOLECULAR-WEIGHT DISTRIBUTION; OLEFIN POLYMERIZATION CATALYSTS; ZIEGLER-NATTA; ALPHA-OLEFIN; PYRIDYLAMIDO HAFNIUM; ZIRCONIUM COMPLEXES; TITANIUM COMPLEXES; DIAMINE-BIS(PHENOLATE) COMPLEXES; STRUCTURAL-CHARACTERIZATION; STYRENE COPOLYMERIZATION;
D O I：
10.3390/polym13244456
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This paper gives a short overview of homogeneous post-metallocene catalysts based on group 4 metal and vanadium complexes bearing multidentate ligands. It summarizes the catalytic behavior of those catalysts in copolymerization of ethylene with 1-olefins, with styrenic monomers and with alpha,omega-alkenols. The review is focused on finding correlations between the structure of a complex, its catalyst activity and comonomer incorporation ability, as well as the microstructure of the copolymer chains.
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页数：27
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