Separation of Heavy Crude Oil Emulsions Using Microwave Radiation for Further Crude Oil Analysis

被引:19
作者
Diehl, Liange O. [1 ]
Moraes, Diogo P. [1 ]
Antes, Fabiane G. [1 ]
Pereira, Juliana S. F. [1 ]
Santos, Maria de Fatima P. [2 ]
Guimaraes, Regina C. L. [3 ]
Paniz, Jose Neri G. [1 ]
Flores, Erico M. M. [1 ]
机构
[1] Univ Fed Santa Maria, Dept Quim, BR-97105900 Santa Maria, RS, Brazil
[2] Univ Fed Espirito Santo, Dept Ciencias Matemat & Nat, Sao Mateus, ES, Brazil
[3] Petrobras SA, Ctr Pesquisas & Desenvolvimento Leopoldo Amer Mig, Rio De Janeiro, Brazil
关键词
demulsification; desalting; dewatering; heavy crude oil emulsion; microwave radiation; ICP-MS; DEMULSIFICATION; SALINITY; TEMPERATURE; STABILITY; SALT;
D O I
10.1080/01496395.2011.560590
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Microwave radiation in closed vessels was used for the separation of heavy crude oil emulsions for further oil characterization. Operational conditions were studied and the following parameters were evaluated: water content, density, viscosity, N, S, V, Ni, and Cl. Using the proposed procedure it was possible to reduce the water and Cl content in crude oil to values lower than 1% and 300 mu gg-1, respectively. It was possible to determine important crude oil properties without interferences caused by excessive water and salt concentrations. The proposed procedure is relatively fast and it was possible to obtain a suitable condition for water and salt removal from heavy crude oil emulsions without using demulsifiers or toxic reagents.
引用
收藏
页码:1358 / 1364
页数:7
相关论文
共 39 条
[1]   Experimental investigation of crude oil desalting and dehydration [J].
Al-Otaibi, M ;
Elkamel, A ;
Al-Sahhaf, T ;
Ahmed, AS .
CHEMICAL ENGINEERING COMMUNICATIONS, 2003, 190 (01) :65-82
[2]  
[Anonymous], 2002, ANN BOOK ASTM STAND
[3]  
[Anonymous], 1999, ANN BOOK ASTM STAND, V03.01
[4]  
[Anonymous], 2000, ANN BOOK ASTM STAND
[5]  
[Anonymous], 2004, ANN BOOK ASTM STAND
[6]  
[Anonymous], 2006, ASTM D 2166Standard test methods for unconfined compressive strength of cohesive soils
[7]   THE DISTRIBUTION AND QUANTITATION OF ORGANONITROGEN COMPOUNDS IN CRUDE OILS AND ROCK PYROLYSATES [J].
BAKEL, AJ ;
PHILIP, RP .
ORGANIC GEOCHEMISTRY, 1990, 16 (1-3) :353-367
[8]   Influence of water level on oil-water separation by residence time distribution curves investigations [J].
Behin, J. ;
Aghajari, M. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2008, 64 (01) :48-55
[9]  
Botto RI, 2002, CAN J ANAL SCI SPECT, V47, P1
[10]   Element speciation analysis of petroleum and related materials [J].
Caumette, Guilhem ;
Lienemann, Charles-Philippe ;
Merdrignac, Isabelle ;
Bouyssiere, Brice ;
Lobinski, Ryszard .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2009, 24 (03) :263-276