Photoresponsive Block Copolymer Photonic Gels with Widely Tunable Photosensitivity by Counter-Ions

被引:32
作者
Ahn, Youshin [1 ,2 ]
Kim, Eunjoo [1 ,2 ]
Hyon, Jinho [1 ,2 ]
Kang, Changjoon [1 ,2 ]
Kang, Youngjong [1 ,2 ]
机构
[1] Hanyang Univ, Dept Chem, Res Inst Nat Sci, Seoul 133791, South Korea
[2] Hanyang Univ, Inst Nano Sci & Technol, Seoul 133791, South Korea
基金
新加坡国家研究基金会;
关键词
photonic crystals; hydrogels; photocrosslinking; counter-ions; tunable photosensitivity; CROSS-LINKING; POLYELECTROLYTE MULTILAYERS; PHASE-TRANSITION; PH SENSORS; CRYSTALS; FILMS; RESONANCE; HYDROGELS; PHENOL; OPALS;
D O I
10.1002/adma.201103767
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Block copolymer photonic crystals comprising polyelectrolyte hydrogels exhibit strong reflective multicolors in response to near-UV radiation. Due to unique volume transition of swollen gels, the photonic gels show high photosensitivity, and which can be widely tunable by exchanging counter-anions. Multicolor photonic patterns created by photolithography can be repeatedly fixated and reactivated by sequentially exchanging counter-anions with different photosensitivity. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:OP127 / OP130
页数:4
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