A NEW METHOD OF INTRODUCING SCH3 AND SCD3 GROUPS TO PHOSPHOROTHIOATES

被引：4

作者：

Liu, Tianzhen ^{[1
]}

Cui, Xiaoxue ^{[1
]}

Yu, Zhifang ^{[1
]}

Li, Chunbao ^{[1
]}

机构：

[1] Tianjin Univ, Coll Sci, Dept Chem, Tianjin 300072, Peoples R China

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2012年 / 187卷 / 05期

关键词：

Synthesis; phosphites; phosphates; deuterium-labeled synthesis; SULFUR; REARRANGEMENT; DERIVATIVES; PHOSPHITES; PHOSPHORUS; MICROWAVE; BONDS;

D O I：

10.1080/10426507.2011.634467

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new synthesis of phosphorothioates starting fromphosphites and cyanuric chloride (TCT)-activated DMSO is reported herein. This method enables the incorporation of SCH3 and SCD3 groups into phosphorothioates in good yields. The labeling purities of the products are excellent.

引用

页码：606 / 611

页数：6

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