VF(C4O4)(H2O)2:: a new layer type of diaquavanadium(III) fluoride squarate

被引：1

作者：

Mohanu, A ^{[1
]}

Trombe, JC ^{[1
]}

机构：

[1] Ctr Elaborat Mat & Etud Struct, CNRS, F-31055 Toulouse 4, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2006年 / 62卷 / 01期

关键词：

Crystal structure - Hydrogen bonds - Hydrothermal synthesis - Single crystals - Water;

D O I：

10.1107/S0108270105039259

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystals of the title compound, poly[diaqua-mu-fluoro-mu-squarato-vanadium(Ill)], [V(C4O4)F(H2O)(2)](n), have been prepared hydrothermally at 423 K. This compound is shown to have a layer-type structure. The V and F atoms are localized on the symmetry centers 2a and 2d, respectively, of the monoclinic system (space group P2(1)/n) and they form infinite chains which are bridged by the squarate group acting as a bidentate ligand in a trans position. Two water molecules complete the octahedral coordination of vanadium(III). The three-dimensionality is ensured by a strong O-H center dot center dot center dot O hydrogen bond.

引用

页码：M16 / M18

页数：3