Examining correlations between composition, structure and properties in zircon-containing raw glazes

被引:25
作者
Atkinson, I. [1 ,2 ]
Smith, M. E. [2 ]
Zaharescu, M. [1 ]
机构
[1] Romanian Acad Bucharest, Inst Phys Chem, Bucharest 060021, Romania
[2] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England
关键词
Chemical properties; Traditional ceramics; Glazes; NMR; ZrSiO4; ALUMINOSILICATE GLASSES; CHEMICAL DURABILITY; PHASE-COMPOSITION; NMR; SPECTROSCOPY; COLOR;
D O I
10.1016/j.ceramint.2011.10.007
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The effects of additions of zircon (5-17 wt%) to conventional single tiring ceramic glazes is examined. The structural and morphological characteristics of the glazes were determined by Scanning Electron Microscopy, X-ray diffraction, infra-red spectroscopy, as well as Al-27 and Si-29 magic angle spinning (MAS) NMR. The presence of zircon microcrystals was revealed by X-ray diffraction (XRD) combined with scanning electron microscopy (SEM) and EDAX microanalysis. The chemical durability of the glasses is revealed to be acceptable for certain practical applications. The color characteristics of the glazes obtained were estimated in the HunterLab system (L*C*h*, emission spectra). The outcomes of the study established correlations between composition, structure and some of the physical properties. (C) 2011 Elsevier Ltd and Techna Group Sri. All rights reserved.
引用
收藏
页码:1827 / 1833
页数:7
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