NMR Studies of Optically Active Schiff Bases

被引：8

作者：

Rozwadowski, Z. ^{[1
]}

机构：

[1] W Pomeranian Univ Technol, Dept Inorgan & Analyt Chem, PL-70065 Szczecin, Poland

来源：

ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 74 | 2011年 / 74卷

关键词：

Schiff bases; Imines; Complexes; Optically active; Equilibria; NMR; CP MAS NMR; SOLID-STATE NMR; C-13; CHEMICAL-SHIFTS; CONFIGURATIONALLY DRIVEN PREORGANIZATION; PM5 SEMIEMPIRICAL CALCULATIONS; TRANSITION-METAL-COMPLEXES; HALF-SANDWICH COMPLEXES; AMINO-ACIDS; ENANTIOMERIC PURITY; SALEN COMPLEXES; RETINYLIDENE CHROMOPHORE;

D O I：

10.1016/B978-0-08-097072-1.00003-0

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The review covers the use of NMR spectroscopy in studies of optically active Schiff bases based on selected results reported in the last decade. The first part of the review is devoted to formation of Schiff bases as products which facilitate determination of the enatiomeric purity of various compounds. The next part is dedicated to conformational studies and investigation of different types of equilibria in optically active Schiff bases. Another part is devoted to studies of selected metal complexes, derivatives of optically active Schiff bases. Results concerning investigation of biologically active compounds in which Schiff bases are formed as intermediate product of enzymatic reactions are presented in separate section.

引用

页码：125 / 180

页数：56

共 50 条

[1] NMR Studies of Hydroxy Schiff Bases
Hansen, P. E.
Rozwadowski, Z.
Dziembowska, T.
CURRENT ORGANIC CHEMISTRY, 2009, 13 (02) : 194 - 215
[2] Chiral recognition of the Schiff bases by NMR spectroscopy in the presence of a chiral dirhodium complex.: Deuterium isotope effect on 13C chemical shift of the optically active Schiff bases and their dirhodium adducts
Rozwadowski, Z.
MAGNETIC RESONANCE IN CHEMISTRY, 2007, 45 (07) : 605 - 610
[3] Synthesis of optically active omeprazole by catalysis with vanadyl complexes with chiral Schiff bases
Koneva, E. A.
Khomenko, T. M.
Kurbakova, S. Yu.
Komarova, N. I.
Korchagina, D. V.
Volcho, K. P.
Salakhutdinov, N. F.
Tolstikov, A. G.
Tolstikov, G. A.
RUSSIAN CHEMICAL BULLETIN, 2008, 57 (08) : 1680 - 1685
[4] Synthesis of optically active omeprazole by catalysis with vanadyl complexes with chiral Schiff bases
E. A. Koneva
T. M. Khomenko
S. Yu. Kurbakova
N. I. Komarova
D. V. Korchagina
K. P. Volcho
N. F. Salakhutdinov
A. G. Tolstikov
G. A. Tolstikov
Russian Chemical Bulletin, 2008, 57 : 1680 - 1685
[5] Schiff bases of gossypol: an NMR and DFT study
That, QT
Nguyen, KPP
Hansen, PE
MAGNETIC RESONANCE IN CHEMISTRY, 2005, 43 (04) : 302 - 308
[6] Chiral recognition of Schiff bases by 15N NMR spectroscopy in the presence of a dirhodium complex.: Deuterium isotope effect on 15N chemical shift of the optically active Schiff bases and their dirhodium tetracarboxylate adducts
Romadowski, Z.
Nowak-Wydra, B.
MAGNETIC RESONANCE IN CHEMISTRY, 2008, 46 (10) : 974 - 978
[7] Experimental and theoretical studies of Schiff bases as corrosion inhibitors
Jamil, Dalia M.
Al-Okbi, Ahmed K.
Al-Baghdadi, Shaimaa B.
Al-Amiery, Ahmed A.
Kadhim, Abdulhadi
Gaaz, Tayser Sumer
Kadhum, Abdul Amir H.
Mohamad, Abu Bakar
CHEMISTRY CENTRAL JOURNAL, 2018, 12
[8] Synthesis and Studies of Novel Optically Active Schiff's Base Derivatives and their Antimicrobial Activities
Patel, Ishwar J.
Parmar, Shailesh J.
E-JOURNAL OF CHEMISTRY, 2010, 7 (02) : 617 - 623
[9] Deprotonation of hydrogen bonded Schiff bases by three strong nitrogen bases
Schilf, Wojciech
Cmoch, Piotr
Szady-Chelmieniecka, Anna
Grech, Eugeniusz
JOURNAL OF MOLECULAR STRUCTURE, 2009, 921 (1-3) : 34 - 37
[10] Hydrogen bonding in Schiff bases - NMR, structural and experimental charge density studies
Makal, Anna
Schilf, Wojciech
Kamienski, Bohdan
Szady-Chelmieniecka, Anna
Grech, Eugeniusz
Wozniak, Krzysztof
DALTON TRANSACTIONS, 2011, 40 (02) : 421 - 430

← 1 2 3 4 5 →