Characteristics of twisted intramolecular charge-transfer state in a hyperbranched conjugated polymer

被引：2

作者：

Yang, JL ^{[1
]}

He, QG ^{[1
]}

Lin, HZ ^{[1
]}

Fan, JJ ^{[1
]}

Bai, FL ^{[1
]}

机构：

[1] Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Lab Organ Solids, Beijing 100080, Peoples R China

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2001年 / 22卷 / 14期

关键词：

D O I：

10.1002/1521-3927(20011001)22:14<1152::AID-MARC1152>3.0.CO;2-A

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A hyperbranched conjugated polymer functionalized in periphery with NN-dimethylaniline was synthesized and characterized. Solvatochromic shifts in both absorption and fluorescence spectra, the effects of solvent polarities on the fluorescence quantum yield and fluorescence lifetime were investigated to probe the formation of an intramolecular charge transfer (ICT) state. The peak position of the emission band arising from the ICT state is red-shifted, and the fluorescence quantum efficiency of the polymer decreases with increasing polarity of the solvents.

引用

页码：1152 / 1157

页数：6

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