A mesoporous ternary transition metal oxide nanoparticle composite for high-performance asymmetric supercapacitor devices with high specific energy

被引:29
作者
Deyab, Nourhan M. [1 ,2 ]
Taha, Manar M. [1 ]
Allam, Nageh K. [1 ]
机构
[1] Amer Univ Cairo, Sch Sci & Engn, Energy Mat Lab, New Cairo 11835, Egypt
[2] Natl Res Ctr, Phys Chem Dept, Giza, Egypt
来源
NANOSCALE ADVANCES | 2022年 / 4卷 / 05期
关键词
NANOTUBE ARRAYS; TIO2; ELECTRODES; ARCHITECTURES; NICKEL;
D O I
10.1039/d1na00694k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report on the optimized fabrication and electrochemical properties of ternary metal oxide (Ti-Mo-Ni-O) nanoparticles as electrochemical supercapacitor electrode materials. The structural, morphological, and elemental composition of the fabricated Ti-Mo-Ni-O via rapid breakdown anodization are elucidated by field emission scanning electron microscopy, Raman, and photoelectron spectroscopy analyses. The Ti-Mo-Ni-O nanoparticles reveal pseudocapacitive behavior with a specific capacitance of 255.4 F g(-1). Moreover, the supercapacitor device Ti-Mo-Ni-O NPs//mesoporous doped-carbon (TMN NPs//MPDC) device exhibited a superior specific energy of 68.47 W h kg(-1) with a corresponding power density of 2058 W kg(-1). The supercapacitor device shows 100% coulombic efficiency with 96.8% capacitance retention over 11 000 prolonged charge/discharge cycles at 10 A g(-1).
引用
收藏
页码:1387 / 1393
页数:7
相关论文
共 45 条
[1]   Recent advances in the use of TiO2 nanotube powder in biological, environmental, and energy applications [J].
Abbas, Walaa A. ;
Abdullah, Ibrahim H. ;
Ali, Basant A. ;
Ahmed, Nashaat ;
Mohamed, Aya M. ;
Rezk, Marwan Y. ;
Ismail, Noha ;
Mohamed, Mona A. ;
Allam, Nageh K. .
NANOSCALE ADVANCES, 2019, 1 (08) :2801-2816
[2]   Titanium vanadium nitride electrode for micro-supercapacitors [J].
Achour, A. ;
Lucio-Porto, R. ;
Chaker, M. ;
Arman, A. ;
Ahmadpourian, A. ;
Soussou, M. A. ;
Boujtita, M. ;
Le Brizoual, L. ;
Djouadi, M. A. ;
Brousse, T. .
ELECTROCHEMISTRY COMMUNICATIONS, 2017, 77 :40-43
[3]  
Ahmed F., 2019, Micromachines, V10, P6, DOI [10.3390/mi10110742, DOI 10.3390/MI10110742]
[4]   Untapped Potential of Polymorph MoS2: Tuned Cationic Intercalation for High-Performance Symmetric Supercapacitors [J].
Ali, Basant A. ;
Omar, Asmaa M. A. ;
Khalil, Ahmed S. G. ;
Allam, Nageh K. .
ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (37) :33955-33965
[5]   Metal oxide-based supercapacitors: progress and prospectives [J].
An, Cuihua ;
Zhang, Yan ;
Guo, Huinan ;
Wang, Yijing .
NANOSCALE ADVANCES, 2019, 1 (12) :4644-4658
[6]   INNER AND OUTER ACTIVE SURFACE OF RUO2 ELECTRODES [J].
ARDIZZONE, S ;
FREGONARA, G ;
TRASATTI, S .
ELECTROCHIMICA ACTA, 1990, 35 (01) :263-267
[7]   Pseudocapacitive oxide materials for high-rate electrochemical energy storage [J].
Augustyn, Veronica ;
Simon, Patrice ;
Dunn, Bruce .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (05) :1597-1614
[8]   Propping the electrochemical impedance spectra at different voltages reveals the untapped supercapacitive performance of materials [J].
Badawy, Ibrahim M. ;
Elbanna, Abdussalam M. ;
Ramadan, Mohamed ;
Allam, Nageh K. .
ELECTROCHIMICA ACTA, 2022, 408
[9]   Porous sulfide scaffolded solvent-free PEG-Ti hybrid polymer: All-solution-processed thin film composite polymer electrolytes directly on electrodes for lithium-ion batteries [J].
Cai, Ting-Jhen ;
Lo, Yi-Hsuan ;
Wu, Jih-Jen .
MATERIALS TODAY ENERGY, 2019, 13 :119-124
[10]   Modification of TiO2 Nanoparticles with Organodiboron Molecules Inducing Stable Surface Ti3+ Complex [J].
Cao, Yang ;
Zhou, Peng ;
Tu, Yongguang ;
Liu, Zheng ;
Dong, Bo-Wei ;
Azad, Aryan ;
Ma, Dongge ;
Wang, Dong ;
Zhang, Xu ;
Yang, Yang ;
Jiang, Shang-Da ;
Zhu, Rui ;
Guo, Shaojun ;
Mo, Fanyang ;
Ma, Wanhong .
ISCIENCE, 2019, 20 :195-+