Investigation of prototypal MOFs consisting of polyhedral cages with accessible Lewis-acid sites for quinoline synthesis

被引：40
作者：
Gao, Wen-Yang [1 ]
Leng, Kunyue [2 ]
Cash, Lindsay [1 ]
Chrzanowski, Matthew [1 ]
Stackhouse, Chavis A. [1 ]
Sun, Yinyong [2 ]
Ma, Shengqian [1 ]
机构：
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
[2] Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 23期
基金：
美国国家科学基金会;
关键词：
METAL-ORGANIC FRAMEWORKS; EFFICIENT HETEROGENEOUS CATALYST; FRIEDLANDER SYNTHESIS; 1,8-NAPHTHYRIDINES; DERIVATIVES; INHIBITORS; DESIGN; MILD; CO2;
D O I：
10.1039/c4cc09410g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of prototypal metal-organic frameworks (MOFs) consisting of polyhedral cages with accessible Lewis-acid sites, have been systematically investigated for Friedlander annulation reaction, a straightforward approach to synthesizing quinoline and its derivatives. Amongst them MMCF-2 demonstrates significantly enhanced catalytic activity compared with the benchmark MOFs, HKUST-1 and MOF-505, as a result of a high-density of accessible Cu(II) Lewis acid sites and large window size in the cuboctahedral cage-based nanoreactor of MMCF-2.
引用
收藏
页码：4827 / 4829
页数：3
相关论文
共 54 条
[1]   NEW CONJUGATED POLYANTHRAZOLINES CONTAINING THIOPHENE MOIETIES IN THE MAIN CHAIN [J].
AGRAWAL, AK ;
JENEKHE, SA .
MACROMOLECULES, 1991, 24 (25) :6806-6808
[2]   Toxic gas removal - metal-organic frameworks for the capture and degradation of toxic gases and vapours [J].
Barea, Elisa ;
Montoro, Carmen ;
Navarro, Jorge A. R. .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5419-5430
[3]   Identification of xanthurenic acid as the putative inducer of malaria development in the mosquito [J].
Billker, O ;
Lindo, V ;
Panico, M ;
Etienne, AE ;
Paxton, T ;
Dell, A ;
Rogers, M ;
Sinden, RE ;
Morris, HR .
NATURE, 1998, 392 (6673) :289-292
[4]   High H2 adsorption in a microporous metal-organic framework with open metal sites [J].
Chen, BL ;
Ockwig, NW ;
Millward, AR ;
Contreras, DS ;
Yaghi, OM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4745-4749
[5]   Biomimetic Catalysis of a Porous Iron-Based Metal-Metalloporphyrin Framework [J].
Chen, Yao ;
Tran Hoang ;
Ma, Shengqian .
INORGANIC CHEMISTRY, 2012, 51 (23) :12600-12602
[6]   Synthesis and antibacterial evaluation of certain quinolone derivatives [J].
Chen, YL ;
Fang, KC ;
Sheu, JY ;
Hsu, SL ;
Tzeng, CC .
JOURNAL OF MEDICINAL CHEMISTRY, 2001, 44 (14) :2374-2377
[7]  
CHENG CC, 1982, ORG REACTIONS, V28, P37
[8]   A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].
Chui, SSY ;
Lo, SMF ;
Charmant, JPH ;
Orpen, AG ;
Williams, ID .
SCIENCE, 1999, 283 (5405) :1148-1150
[9]   Luminescent Functional Metal-Organic Frameworks [J].
Cui, Yuanjing ;
Yue, Yanfeng ;
Qian, Guodong ;
Chen, Banglin .
CHEMICAL REVIEWS, 2012, 112 (02) :1126-1162
[10]   An efficient and rapid approach to quinolines via Friedlander synthesis catalyzed by silica gel supported sodium hydrogen sulfate under solvent-free conditions [J].
Dabiri, Minoo ;
Azimi, Seyyedeh Cobra ;
Bazgir, Ayoob .
MONATSHEFTE FUR CHEMIE, 2007, 138 (07) :659-661
123456