Yellowish White-Light Emission Involving Resonant Energy Transfer in a New One-Dimensional Hybrid Material: (C9H10N2)PbCl4

被引:64
作者
Barkaoui, H. [1 ]
Abid, H. [1 ]
Yangui, A. [2 ]
Triki, S. [3 ]
Boukheddaden, K. [4 ]
Abid, Y. [1 ]
机构
[1] Fac Sci Sfax, Lab Phys Appl, Route Soukra Km 3-5,BP 1171, Sfax 3018, Tunisia
[2] Univ Tokyo, Inst Ind Sci, Meguro Ku, 4-6-1 Komaba, Tokyo 1538505, Japan
[3] Univ Brest UBO, CNRS, UMR 6521, 6 Ave Victor Le Gorgeu,CS 93837, F-29238 Brest 3, France
[4] Univ Paris Saclay, Univ Versailles St Quentin Yvelines, CNRS, UMR 8653,Grp Etud Matiere Condensee, 45 Ave Etats Unis, F-78035 Versailles, France
关键词
ORGANIC-INORGANIC PEROVSKITES; ELECTRONIC-STRUCTURE CALCULATIONS; ORGANOMETAL HALIDE PEROVSKITES; COLOR RENDERING INDEX; BROAD-BAND EMISSION; OPTICAL-PROPERTIES; SOLAR-CELLS; QUANTUM DOTS; THIN-FILM; SEMICONDUCTORS;
D O I
10.1021/acs.jpcc.8b06850
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present work deals with a new one-dimensional (1D) organic-inorganic hybrid material, namely (C9H10N2)PbCl4 (abbreviated as AQPbCl(4)). Its crystal structure is built up from the infinite 1D chain of edge-sharing PbCl6 octahedra surrounded by 3-aminoquinoline (abbreviated as AQ) organic molecules. Contrary to the most organic-inorganic hybrid materials, where the organic moieties act as barriers and the inorganic parts play the role of quantum wells, both inorganic and organic parts in AQPbCl(4) are optically active, giving rise to optical properties involving the competition and the interaction of two organic and inorganic emitting entities. Under UV excitation, this hybrid compound shows a strong yellowish white-light emission that can be seen even with the naked eye and at room temperature. The photoluminescence spectrum is composed of a strong and broad yellow band at 538 nm associated with pi-pi* transition localized within the AQ organic molecule and a less intense band in the UV region at 340 nm associated with an inorganic Wannier exciton confined in the PbCl4 inorganic wires. These attributions were made possible thanks to comparisons with homologous materials, and they were supported by theoretical band structure calculations. In addition, both theoretical and experimental investigations suggest that emission involves a resonant energy transfer mechanism in which the inorganic PbCl4 wires act as donor, and the organic cations act as acceptor. Moreover, the temperature dependence study of photoluminescence led to an estimation of the binding energies of interacting excitons and showed that the energy transfer mechanism is characterized by a remarkable enhancement of the emission band intensity.
引用
收藏
页码:24253 / 24261
页数:9
相关论文
共 83 条
[1]   Spectroscopic ellipsometry thin film and first-principles calculations of electronic and linear optical properties of [(C9H19NH3)2PbI2Br2] 2D perovskite [J].
Abid, H. ;
Hlil, E. K. ;
Abid, Y. .
JOURNAL OF SOLID STATE CHEMISTRY, 2017, 247 :131-136
[2]   Electronic structure calculations and optical properties of a new organic-inorganic luminescent perovskite: (C9H19NH3)2PbI2Br2 [J].
Abid, H. ;
Samet, A. ;
Dammak, T. ;
Mlayah, A. ;
Hlil, E. K. ;
Abid, Y. .
JOURNAL OF LUMINESCENCE, 2011, 131 (08) :1753-1757
[3]   Hybrid Resonant Organic Inorganic Nanostructures for Optoelectronic Applications [J].
Agranovich, V. M. ;
Gartstein, Yu. N. ;
Litinskaya, M. .
CHEMICAL REVIEWS, 2011, 111 (09) :5179-5214
[4]   A simple effective potential for exchange [J].
Becke, Axel D. ;
Johnson, Erin R. .
JOURNAL OF CHEMICAL PHYSICS, 2006, 124 (22)
[5]   Organic-inorganic hybrids: From magnetic perovskite metal(II) halides to multifunctional metal(II) phosphonates [J].
Bellitto, Carlo ;
Bauer, Elvira M. ;
Righini, Guido .
COORDINATION CHEMISTRY REVIEWS, 2015, 289 :123-136
[6]   Bis(pentane-1,5-diammonium) decaiodotriplumbate(II) [J].
Billing, DG ;
Lemmerer, A .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 :M224-M226
[7]  
Blaha P., 2001, AUGMENTED PLANE WAVE, V2
[8]   IMPROVED TETRAHEDRON METHOD FOR BRILLOUIN-ZONE INTEGRATIONS [J].
BLOCHL, PE ;
JEPSEN, O ;
ANDERSEN, OK .
PHYSICAL REVIEW B, 1994, 49 (23) :16223-16233
[9]   Converting Wannier into Frenkel excitons in an inorganic/organic hybrid semiconductor nanostructure [J].
Blumstengel, S. ;
Sadofev, S. ;
Xu, C. ;
Puls, J. ;
Henneberger, F. .
PHYSICAL REVIEW LETTERS, 2006, 97 (23)
[10]   Tailoring of energy levels in lead chloride based layered perovskites and energy transfer between the organic and inorganic planes [J].
Braun, M ;
Tuffentsammer, W ;
Wachtel, H ;
Wolf, HC .
CHEMICAL PHYSICS LETTERS, 1999, 303 (1-2) :157-164