High performance Cu-ZnO/Pd-β catalysts for syngas to LPG

被引：30

作者：

Ge, Qingjie ^{[1
]}

Lian, Yu ^{[1
]}

Yuan, Xingdong ^{[1
]}

Li, Xiaohong ^{[1
]}

Fujimoto, Kaoru ^{[1
]}

机构：

[1] Univ Kitakyushu, Fac Environm Engn, Fukuoka 8080135, Japan

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 02期

关键词：

synthesis gas; LPG synthesis; Cu-ZnO/Pd-beta catalysts;

D O I：

10.1016/j.catcom.2007.06.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic performance of Cu-ZnO/Pd-beta catalyst for syngas to LPG (Liquefied Petroleum Gas) has been investigated in this paper. The kind of zeolite, SiO2/Al2O3 ratio in Pd-beta, Pd-beta particle size, Pd content in Pd-beta, and reaction conditions, have been optimized. The results showed that the suitable reaction conditions for syngas to LPG over Cu-ZnO/Pd-beta are: 325-350 degrees C, 2.1-3.6 MPa, 4.5-9 g h/mol gas velocity (W/F), and 37-75 ratio of SiO2/Al2O3. At the optimal conditions, Cu-ZnO/Pd-beta could exhibit ail excellent catalytic performance for syngas to LPG: 72.2% CO conversion, 45.3% hydrocarbon yield and 78.0% LPG selectivity in hydrocarbons could be achieved. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：256 / 261

页数：6

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