Vinyl Dibromides: Versatile Partners in Cross-Coupling Reactions

被引：45
作者：
Legrand, Frederic [1 ]
Jouvin, Kevin [1 ]
Evano, Gwilherm [1 ]
机构：
[1] Univ Versailles, Inst Lavoisier Versailles, CNRS, UMR 8180, F-78035 Versailles, France
来源：
ISRAEL JOURNAL OF CHEMISTRY | 2010年 / 50卷 / 5-6期
关键词：
cross-coupling; homogeneous catalysis; reactivity; site-selective reactions; total synthesis; vinyl dibromides; ONE-POT SYNTHESIS; TRISUBSTITUTED CONJUGATED DIENES; HIGHLY SELECTIVE SYNTHESIS; SEQUENTIAL SUZUKI-MIYAURA; DIRECTING GROUP STRATEGY; STEREOSELECTIVE-SYNTHESIS; STEREOCONTROLLED SYNTHESIS; EFFICIENT SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; BOTTOM HALF;
D O I：
10.1002/ijch.201000037
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Once limited to the preparation of alkynes, the chemistry of 1,1-dibromoalkenes has clearly undergone a renaissance through the application of palladium and copper catalysis. Remarkably efficient, innovative, and reliable methods have been recently designed around this chemistry, which has found many applications for the preparation of sophisticated building blocks as well as natural and/or biologically active products. This review article highlights major developments in this area.
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页码：588 / 604
页数：17
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