Nitrogen-doped carbon nanofibers derived from polypyrrole coated bacterial cellulose as high-performance electrode materials for supercapacitors and Li-ion batteries

被引:62
作者
Lei, Wen [1 ]
Han, Lili [2 ,3 ]
Xuan, Cuijuan [1 ]
Lin, Ruoqian [2 ,4 ]
Liu, Hongfang [1 ]
Xin, Huolin L. [2 ]
Wang, Deli [1 ]
机构
[1] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Hubei Key Lab Mat Chem & Serv Failure, Key Lab Mat Chem Energy Convers & Storage,Minist, Wuhan 430074, Peoples R China
[2] Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11973 USA
[3] Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China
[4] SUNY Stony Brook, Dept Mat Sci & Engn, Stony Brook, NY 11794 USA
基金
国家教育部博士点专项基金资助;
关键词
supercapacitors; Li-ion batteries; polypyrrole; bacterial cellulose; nitrogen-doping; HIERARCHICAL POROUS CARBON; ELECTROCHEMICAL CAPACITORS; GRAPHENE; NANOCOMPOSITES; OXIDE; DENSITY;
D O I
10.1016/j.electacta.2016.05.158
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Nitrogen-doped carbon nanofiber (NDCN) was synthesized via carbonization of polypyrrole (PPy) coated bacterial cellulose (BC) composites, where BC serves as templates as well as precursor, and PPy serves as the nitrogen source. The synthesized NDCN was employed as electrode for both supercapacitors and Li-ion batteries. The large surface area exposed to electrolyte resulting from the 3D carbon networks leads to sufficient electrode/electrolyte interface and creates shorter transport paths of electrolyte ions and Li+ ion. Besides, the three types of N dopants in NDCN improve the electronic conductivity, as well as superior electrochemical performance. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:130 / 137
页数:8
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