Chiral 3D Coordination Polymers Consisting of Achiral Terpyridyl Precursors: from Spontaneous Resolution to Enantioenriched Induction

被引：16

作者：

Zuo, Tao ^{[1
]}

Luo, Dong ^{[1
]}

Huang, Yong-Liang ^{[1
]}

Li, Yan Yan ^{[1
]}

Zhou, Xiao-Ping ^{[1
]}

Li, Dan ^{[1
]}

机构：

[1] Jinan Univ, Coll Chem & Mat Sci, Guangzhou 510632, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2020年 / 26卷 / 09期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

chiral coordination polymers; chiral induction; circular dichroism; self-assembly; terpyridine; METAL-ORGANIC FRAMEWORKS; MICROPOROUS FRAMEWORK; ASYMMETRIC CATALYSIS; OPTICAL RESOLUTION; SYMMETRY-BREAKING; CRYSTALLIZATION; MOLECULES; CAGES;

D O I：

10.1002/chem.201905091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A pair of enantiomers of three-dimensional (3D) chiral coordination polymers (CCPs) were successfully constructed by using achiral components 4,2 ':6 ',4 ''-terpyridyl precursors and Cu2+ through spontaneous resolution (1 a). By utilising feeding controlled chiral-templated induction and chiral auxiliary behaviour of optically pure camphor sulfonate (CSA), the enantioenriched (1 b-P and 1 b-M) and CSA captured (1 c-P and 1 c-M) CCPs were successfully synthesised, respectively. The chiral information of the corresponding products was confirmed by X-ray single crystal diffraction and solid-state CD spectra. Meanwhile, the formation processes of 1 b-P and 1 b-M were monitored through solution CD spectra, UV/Vis spectra and ESI-TOF MS. Based on these results, a reasonable chiral-templated induction mechanism of forming 1 b-P and 1 b-M was proposed.

引用

页码：1936 / 1940

页数：5

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