Chiral 3D Coordination Polymers Consisting of Achiral Terpyridyl Precursors: from Spontaneous Resolution to Enantioenriched Induction

被引：17

作者：

Zuo, Tao ^{[1
]}

Luo, Dong ^{[1
]}

Huang, Yong-Liang ^{[1
]}

Li, Yan Yan ^{[1
]}

Zhou, Xiao-Ping ^{[1
]}

Li, Dan ^{[1
]}

机构：

[1] Jinan Univ, Coll Chem & Mat Sci, Guangzhou 510632, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2020年 / 26卷 / 09期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

chiral coordination polymers; chiral induction; circular dichroism; self-assembly; terpyridine; METAL-ORGANIC FRAMEWORKS; MICROPOROUS FRAMEWORK; ASYMMETRIC CATALYSIS; OPTICAL RESOLUTION; SYMMETRY-BREAKING; CRYSTALLIZATION; MOLECULES; CAGES;

D O I：

10.1002/chem.201905091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A pair of enantiomers of three-dimensional (3D) chiral coordination polymers (CCPs) were successfully constructed by using achiral components 4,2 ':6 ',4 ''-terpyridyl precursors and Cu2+ through spontaneous resolution (1 a). By utilising feeding controlled chiral-templated induction and chiral auxiliary behaviour of optically pure camphor sulfonate (CSA), the enantioenriched (1 b-P and 1 b-M) and CSA captured (1 c-P and 1 c-M) CCPs were successfully synthesised, respectively. The chiral information of the corresponding products was confirmed by X-ray single crystal diffraction and solid-state CD spectra. Meanwhile, the formation processes of 1 b-P and 1 b-M were monitored through solution CD spectra, UV/Vis spectra and ESI-TOF MS. Based on these results, a reasonable chiral-templated induction mechanism of forming 1 b-P and 1 b-M was proposed.

引用

页码：1936 / 1940

页数：5

共 50 条

[31] ZnII/CdII-coordination polymers from 1D chain, 2D layer to 3D framework with imidazole-based dicarboxylate ligand [J].

Dong, Wen-Wen ;

Li, Dong-Sheng ;

Zhao, Jun ;

Wu, Ya-Pan ;

Meng, Cai-Xia ;

Wang, Yao-Yu .

INORGANICA CHIMICA ACTA, 2012, 384 :260-265

[32] Chiral Coordination Polymers from a New 2-Deoxy-D-ribose Derivative Linker: Syntheses, Structures, and Fe3+ Fluorescent Probe Functions [J].

He, Tian-Sheng ;

Lan, Yan-Long ;

Li, Zong-Ying ;

Zhu, Li-Na ;

Li, Xiao-Zeng .

CRYSTAL GROWTH & DESIGN, 2021, 21 (04) :2233-2242

[33] Two novel 3D lanthanide supramolecular coordination polymers constructed from paddle wheel SBUs and hydrogen bonding: synthesis, structures and properties [J].

Li, Qipeng ;

Du, Shaowu .

RSC ADVANCES, 2014, 4 (59) :30963-30967

[34] Homochiral zinc benzene-1,3,5-tricarboxylate coordination networks with a chiral nitrogen ligand or template: Spontaneous resolution of a twofold interpenetrated 2D sql (4,4) network and formation of enantiopure 3D sra (SrAl2) networks [J].

Tahli, Anas ;

Chamayou, Anne-Christine ;

Koc, Umit ;

Bruckner, Robin ;

Elshaarawy, Reda F. M. ;

Heering, Christian ;

Janiak, Christoph .

INORGANICA CHIMICA ACTA, 2016, 450 :190-201

[35] 2D and 3D lanthanide coordination polymers constructed from benzimidazole-5,6-dicarboxylic acid and sulfate bridged secondary building units [J].

Wang, Zhao-Xi ;

Wu, Qiong-Fang ;

Liu, Hong-Jiang ;

Shao, Min ;

Xiao, Hong-Ping ;

Li, Ming-Xing .

CRYSTENGCOMM, 2010, 12 (04) :1139-1146

[36] Structural Modulation from 1D Chain to 3D Framework: Improved Thermostability, Insensitivity, and Energies of Two Nitrogen-Rich Energetic Coordination Polymers [J].

Guo, Zhaoqi ;

Wu, Yunlong ;

Deng, Chongqing ;

Yang, Guoping ;

Zhang, Jiangong ;

Sun, Zhihua ;

Ma, Haixia ;

Gao, Chao ;

An, Zhongwei .

INORGANIC CHEMISTRY, 2016, 55 (21) :11064-11071

[37] From 1D to 3D lanthanide coordination polymers constructed with pyridine-3,5-dicarboxylic acid: synthesis, crystal structures, and catalytic properties [J].

Lin, Xiao-Ming ;

Niu, Ji-Liang ;

Wen, Pei-Xian ;

Lu, Yan-Na ;

Hu, Lei ;

Zhang, Da-Liang ;

Cai, Yue-Peng .

RSC ADVANCES, 2016, 6 (68) :63425-63432

[38] Mechanochemical Synthesis of 3d Transition-Metal-1,2,4-Triazole Complexes as Precursors for Microwave-Assisted and Thermal Conversion to Coordination Polymers with a High Influence on the Dielectric Properties [J].

Brede, Franziska A. ;

Heine, Johanna ;

Sextl, Gerhard ;

Mueller-Buschbaum, Klaus .

CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (08) :2708-2718

[39] Tuning topological and dimensional versatility from 1D to 3D of Zn/Cd luminescent biphenyl-3,5-dicarboxylate coordination polymers by ancillary ligand [J].

Huang, Wei ;

Jiang, Jun ;

Xu, Jun ;

Kirillov, Alexander M. ;

Wu, Dayu .

JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (14) :2200-2209

[40] Construction of 1D to 3D cadmium(II) coordination polymers from 4-(imidazol-1-yl)-benzoic acid: Effect of bridging anions [J].

Feng, Ying ;

Wang, Da-Bin ;

Wan, Bo ;

Li, Xin-Hua ;

Shi, Qian .

INORGANICA CHIMICA ACTA, 2014, 413 :187-193

← 1 2 3 4 5 →